Grundinformationen
- Standard-SMILES
CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1- InChIKey
HSLFISVKRDQEBY-UHFFFAOYSA-N- Summenformel
- C14H28O4
- Durchschnittliche Molmasse
- 260,37 g/mol
- Monoisotopische Masse
- 260,19875938
Überblick
Organic solvent solution, added to lessen explosion hazard.
Namen und Bezeichner
- Bevorzugter Name
- 1,1-Bis(tert-butylperoxy)cyclohexane
- IUPAC
- 1,1-bis(tert-butylperoxy)cyclohexane
- Lokaler Name
- cyclohexylidenbis[tert-butyl]peroxid
- Englischer Name
- 1,1-Di(tert-butylperoxy)cyclohexane
- Summenformel
- C14H28O4
- Molmasse
- 260.37
Namen und Synonyme
1,1-Bis(tert-butylperoxy)cyclohexane3006-86-8Cyclohexylidenebis(tert-butyl) peroxideUNII-JK62J3E3Q4JK62J3E3Q4EINECS 221-111-2PERHEXA CSLuperox 331M80Peroxide, 1,1'-cyclohexylidenebis(2-(1,1-dimethylethyl)EC 221-111-2PERHEXA C 40PERHEXA C 75
Weitere Namen anzeigen
1,1-bis(T-butylperoxy)cyclohexaneDP275BPerhexa-CChaloxyd PTrigonox 22Lupersol 331TRIGONOX(R) 22Luperox? 331P80
PEROXAN PK 122WTRIGONOX 22C50TRIGONOX 22E50TRIGONOX 22E70LUPEROX 331DTXSID4044907TX 22E50Cyclohexylidenebis[tert-butyl] peroxide
Datenbank-Bezeichner
- CAS
3006-86-8- PubChem CID
- 76359
- DTXSID
DTXSID4044907- UNII
- JK62J3E3Q4
- EC Number
- 221-111-2
- Nikkaji
- J4.394J
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 3,7
- Polarare Oberfläche (TPSA)
- 36,9 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 4
- Frei drehbare Bindungen
- 6
- Schwere Atome
- 18
- Formalladung
- 0
- Komplexität
- 224
Experimentelle und physikochemische Eigenschaften
Physical Description
Organic solvent solution, added to lessen explosion hazard.
Particularly heat and contamination sensitive.
CBI; Liquid
Physikochemische Eigenschaften
- Schmelzpunkt
- 65 °C · 65 °C (SADT)
- Siedepunkt
- 52 · 52-54 °C (0.1 mmHg)
- Dichte
- 0.891 g/mL · 0.891 g/mL at 25 °C
- Dampfdruck
- 4.88 hPa · 4.88hPa at 25℃
- Brechungsindex
- 20 · n20/D 1.435
- Flammpunkt
- 155 °F · 155 °F
- storage temp.
- 2 · 2-8°C
- Aggregatzustand
- Liquid
- Farbe
- Clear
- Wasserlöslichkeit
- miscible
- InChI
- InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3
- InChIKey
- HSLFISVKRDQEBY-UHFFFAOYSA-N
- SMILES
- C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C
- LogP
- 7.2 at · 7.2 at 25℃
- CAS Datenbank
- 3006 · 3006-86-8(CAS DataBase Reference)
- EPA chemische Informationen
- 1 · Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 1.8% (3 of 170) of reports.
Danger
H242 (74.7%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]
P210, P234, P235, P240, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 170 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
Gefahrenhinweise
Regulatory Information
Chemical: Peroxide, cyclohexylidenebis[(1,1-dimethylethyl)
Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 15-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5875
Peroxide, cyclohexylidenebis(1,1-dimethylethyl): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
DOT Label
Organic Peroxide
Organic Peroxide
Organic Peroxide
Organic Peroxide Explosive
Fire Hazards
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Health Hazards
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Reactive Group
Peroxides, Organic
Peroxides, Organic
Peroxides, Organic
Peroxides, Organic
Reactivity Alerts
Strong Oxidizing Agent
Strong Oxidizing Agent
Explosive
Explosive
Reactivity Profile
The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]
The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]
The explosive instability of the lower dialkyl peroxides (e.g.,. dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]
The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the mono functional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]
Air and Water Reactions
No rapid reaction with air. No rapid reaction with water.
No rapid reaction with air. No rapid reaction with water.
No rapid reaction with air. No rapid reaction with water.
No rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories
Org. Perox. C (74.7%)
Flammable liquids - Category 4
Sicherheit und Schutzausrüstung
Fire Fighting
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
First Aid
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Nonfire Spill Response
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Isolation and Evacuation
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Personal Protective Equipment (PPE)
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Sicherheitsdaten
- wgk
- 2
- tsca
- TSCA listed
- ridadr
- UN 3103 5.2
- hs_code
- 29096000
- risk_code
- 7-62-50/53-36/37/38-61-65-45-51/53
- hazard_code
- O,N,T
- safety_code
- 17-36/37/39-3/7-14A-61-60-45-26-14-53-62
- hazard_class
- 5.2
- packing_group
- II
- Speicherklasse
- 4.1A - Other explosive hazardous materials
- Hazard Classifications
- Asp. Tox. 1Carc. 1BEye Irrit. 2Muta. 1BOrg. Perox. CSkin Irrit. 2STOT SE 3
Chemie und Industrie
Verwendung und Herstellung
U.S. Production2023: 1,000,000 - <2,500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesCBI
General Manufacturing Information
Plastics Material and Resin Manufacturing
Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl): ACTIVE
Anwendungen
VerwendenPolymerization initiator.
Anbieter50 Anbieter
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Ergänzende Hinweise
Definition1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1].
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