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N-Methylhydroxylaminhydrochlorid
42229-44-1 · N-Methylhydroxylamin · N-METHYLHYDROXYAMINEHCL · N-METHYLHYDROXYLAMINE HCL · Methyl hydroxylamine .HCL · Methylhydroxylammonium chloride · N-Methylhydroxyaminehydrochloride · N-METHYLHYDROXYLAMMONIUM CHLORIDE
Identifikatoren & physikalische Daten
| CAS No. | 4229-44-1 |
|---|---|
| Summenformel | CH5NO.ClH |
| Durchschnittliche Molmasse | 83,52 g/mol |
| Monoisotopische Masse | 83,01379149 g/mol |
| SMILES | CNO.Cl |
| InChIKey | RGZRSLKIOCHTSI-UHFFFAOYSA-N |
| PubChem CID | 77906 |
| EC No. | 224-181-2 |
| DTXSID | DTXSID5063368 |
| Lokaler Name | N-Methylhydroxylaminhydrochlorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 32,3 |
|---|---|
| H-Brücken-Donoren | 3 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 4,8 |
| Stoffklassen | Nitrogen Compounds -> Hydroxylamines |
| Physical Description | Beige hygroscopic crystalline solid[Sigma-Aldrich MSDS] |
| Schmelzpunkt | 86-88 °C(lit.) |
| Dichte | 1.36 g/cm3 |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Löslichkeit | H2O: 0.1 g/mL, clear, very faintly yellowsoluble |
| Aggregatzustand | solid |
| Farbe | white |
| BRN | 3541409 |
| InChI | InChI=1S/CH5NO.ClH/c1-2-3/h2-3H,1H3 |
| InChIKey | RGZRSLKIOCHTSI-UHFFFAOYSA-N |
| SMILES | N(O)C.Cl |
| CAS Datenbank | 4229-44-1(CAS DataBase Reference) |
| EPA chemische Informationen | Methanamine, N-hydroxy-, hydrochloride (4229-44-1) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 47 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Methanamine, N-hydroxy-, hydrochlorideMethanamine, N-hydroxy-, hydrochloride: Does not have an individual approval but may be used under an appropriate group standard |
| Weitere Sicherheitsinformationen | Evaluation - Chemicals not considered for in depth evaluation - Not commercially active in Australia |
| Gefahrenübersicht | A skin and strong eye irritant[Sigma-Aldrich MSDS] |
| Hazard Classes and Categories | Skin Irrit. 2 (100%) |
| F | 3-10 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | 1759 |
| Zollcode | 29280090 |
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-36-24/25 |
| Gefahrenklasse | 8Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
| Verpackungsgruppe | III |
| Lagerklasse | 11 - Combustible Solids |
Anwendungen & Verwendung
Verwenden
N-Methylhydroxylamine hydrochloride is used as an inorganic catalyst used in the transamidation of primary amides with amines. It is employed in constructing hydroxamates, important functional groups for the complexation of iron.