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Bis(2-ethylhexyl)-amin
DIISOOCTYLAMINE · D2H · DI2 EHA · is2-ethylhexyl · DIETHYLHEXYLAMINE · 4-Difluorobenzoate · Two isooctyl amine · Two-ethylhexyl aMine
Identifikatoren & physikalische Daten
| CAS No. | 106-20-7 |
|---|---|
| Summenformel | C16H35N |
| Durchschnittliche Molmasse | 241,46 g/mol |
| Monoisotopische Masse | 241,27695012 g/mol |
| SMILES | CCCCC(CC)CNCC(CC)CCCC |
| InChIKey | SAIKULLUBZKPDA-UHFFFAOYSA-N |
| PubChem CID | 7791 |
| ChEMBL | CHEMBL1330355 |
| ChEBI | CHEBI:193588 |
| EC No. | 203-372-4 |
| DTXSID | DTXSID7025053 |
| Lokaler Name | Bis(2-ethylhexyl)-amin |
Chemische & physikalische Eigenschaften
| XLogP | 6,1 |
|---|---|
| Polarare Oberfläche (TPSA) | 12 |
| H-Brücken-Donoren | 1 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 12 |
| Schwere Atome | 17 |
| Formalladung | 0 |
| Komplexität | 128 |
| Stoffklassen | Nitrogen Compounds -> Amines, Aliphatic |
| Kosmetika | Personal care productAntistaticHair conditioning |
| SpringerMaterials Properties | Optical coefficient |
| Dichte | 0.8062 at 68 °F (NTP, 1992) - Less dense than waterwill float0.805 g/mL at 25 °C(lit.) |
| Löslichkeit | less than 1 mg/mL at 70 °F (NTP, 1992)0.014g/l<0.2 g/L (20 ºC) |
| Flammpunkt | 270 °F (NTP, 1992)>230 °F |
| Siedepunkt | 538 °F at 760 mmHg (NTP, 1992)123 °C5 mm Hg(lit.) |
| Dampfdichte | 8.35 (NTP, 1992) - Heavier than airwill sink (Relative to Air) |
| Dampfdruck | 0.01 mmHg at 68 °F (NTP, 1992)0.01 [mmHg]0.0023 hPa (20 °C) |
| Physical Description | 2,2'-diethylhexylamine is a clear colorless liquid with a slight ammonia-like odor. (NTP, 1992)Clear colorless liquid with a slight ammonia-like odor[CAMEO] |
| Schmelzpunkt | -60 °C |
| Brechungsindex | n20/D 1.443(lit.) |
| Lagerbedingungen | Store below +30°C. |
| pKa (Säurekonstante) | 40(at 25℃) |
| Aggregatzustand | Liquid |
| Farbe | Clear colorless to slightly yellow |
| Wichte | 0.804 (20/4℃) |
| pH | >7 (H2O, 20℃) |
| Explosionsgrenze | 0.6-3.7%(V) |
| BRN | 1748342 |
| Stabilität | Stable. Combustible. Incompatible with oxidizing agents. |
| Kosmetik-Inhaltsstoffe Funktionen | ANTISTATIC |
| InChI | 1S/C16H35N/c1-5-9-11-15(7-3)13-17-14-16(8-4)12-10-6-2/h15-17H,5-14H2,1-4H3 |
| InChIKey | SAIKULLUBZKPDA-UHFFFAOYSA-N |
| SMILES | CCCCC(CC)CNCC(CC)CCCC |
| LogP (Verteilungskoeffizient) | 7.3 at 25℃ |
| CAS Datenbank | 106-20-7(CAS DataBase Reference) |
| NIST chemische Informationen | 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-(106-20-7) |
| EPA chemische Informationen | Di(2-ethylhexyl)amine (106-20-7) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 0.1% (1 of 669) of reports.DangerH302+H312 (65.9%): Harmful if swallowed or in contact with skin [Warning Acute toxicity, oralacute toxicity, dermal]P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P320, P321, P330, P361+P364, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 669 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Not Classified |
|---|---|
| Regulatorische Informationen | Chemical: 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)-1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1-Hexanamine, 2-ethyl-N-(2-ethylhexyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 13-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5450Bis(2-ethylhexyl) amine: Does not have an individual approval but may be used under an appropriate group standard |
| DOT-Kennzeichnung | Corrosive |
| Brandgefahren | This chemical is combustible. (NTP, 1992) |
| Gesundheitsgefahren | SYMPTOMS: Symptoms of exposure to this compound may include irritation to the skin and eyes. |
| Gefahrenübersicht | A skin and eye irritantA lachrymator[CAMEO] Toxic by inhalationHarmful if skin contact or ingestedCauses burnsMay cause pneumonitis and pulmonary edema after inhalation of high concentrations[MSDSonline] |
| Reaktive Gruppe | Amines, Phosphines, and Pyridines |
| Reactivity Profile | 2,2'-DIETHYLHEXYLAMINE can react with oxidizing materials (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
| Air and Water Reactions | Insoluble in water. |
| Hazard Classes and Categories | Acute Tox. 4 (99.7%) |
| Brandbekämpfung | Fires involving this material can be controlled with a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992) |
| Erste Hilfe | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
| Freisetung ohne Brand | SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| Isolation and Evacuation | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
| Personal Protective Equipment (PPE) | RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992) |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
| Toxicity Data | LC50 (rat) = 920 mg/m3/4H[MSDSonline] |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2735 8/PG 2 |
| Zollcode | 29211980 |
| RTECS-Nr. | IH6825000 |
| R-Sätze (R) | 21/22-34 |
| Toxizität | LD50 orally in Rabbit: 1008 mg/kg LD50 dermal Rabbit 956 mg/kg |
| Gefahrensymbole | C,Xi |
| hazard_note | Irritant/Corrosive |
| Sicherheitshinweise (S) | 26-36/37/39-45-36 |
| Gefahrenklasse | 8Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 4 OralAquatic Chronic 1Eye Dam. 1Skin Corr. 1B |
| Verpackungsgruppe | III |
| Lagerklasse | 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials |
| Selbstentzündungstemperatur | 230 °C |
Anwendungen & Verwendung
Verwenden
Bis(2-ethylhexyl)amine (BEA) was used in the synthesis of stable nanosized CdS particles coated by an oriented monolayer of chemically bonded BEA molecules