HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Vinylchlorformiat
Ethenyl carbonochloridate · Vinyl chloroformate · Vinyl chlorocarbonate · Vinylchloroformate99% · Vinyl chloroformate 98% · Vinyloxycarbonyl chloride · VINYL CHLOROFORMATE, STAB. · Ethenyl carbonochloridoate
Identifikatoren & physikalische Daten
| CAS No. | 5130-24-5 |
|---|---|
| Summenformel | C3H3ClO2 |
| Durchschnittliche Molmasse | 106,51 g/mol |
| Monoisotopische Masse | 105,98215702 g/mol |
| SMILES | C=COC(=O)Cl |
| InChIKey | PQLFROTZSIMBKR-UHFFFAOYSA-N |
| PubChem CID | 78808 |
| EC No. | 225-874-2 |
| DTXSID | DTXSID30199299 |
| Lokaler Name | Vinylchlorformiat |
Chemische & physikalische Eigenschaften
| XLogP | 1,7 |
|---|---|
| Polarare Oberfläche (TPSA) | 26,3 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 2 |
| Schwere Atome | 6 |
| Formalladung | 0 |
| Komplexität | 69,2 |
| Stoffklassen | Toxic Gases & Vapors -> Acid Halides |
| Dampfdruck | 45.5 [mmHg]0.88 psi ( 20 °C) |
| Physical Description | Colorless liquid[Alfa Aesar MSDS] |
| Siedepunkt | 68-69 °C735 mm Hg(lit.) |
| Dichte | 1.166 g/mL at 20 °C(lit.) |
| Brechungsindex | n20/D 1.41(lit.) |
| Flammpunkt | 24 °F |
| Lagerbedingungen | 2-8°C |
| Aggregatzustand | Liquid |
| Farbe | Clear colorless |
| BRN | 1741679 |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]P210, P233, P240, P241, P242, P243, P260, P261, P262, P264, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Carbonochloridic acid, ethenyl ester |
| Weitere Sicherheitsinformationen | Evaluation - Chemicals that are unlikely to require further regulation to manage risks to human health |
| Gefahrenübersicht | Reacts with waterCauses burnsInhalation may cause corrosive injuries to upper respiratory tractToxic by ingestion, inhalation, and skin absorption[Alfa Aesar MSDS] See Allyl chloroformate. |
| Hazard Classes and Categories | Flam. Liq. 2 (100%) |
| Expositionsschutz und Persönliche Schutzausrüstung | TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016]. |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
| F | 10-21-19 |
| Wassergefährdungsklasse (WGK) | 3 |
| UN-Transportnummer | UN 3390 6.1/PG 1 |
| Zollcode | 29159000 |
| R-Sätze (R) | 23/24/25-34-11 |
| Gefahrensymbole | F,T |
| Sicherheitshinweise (S) | 16-26-36-45-36/37 |
| Gefahrenklasse | 6.1(a) |
| Verpackungsgruppe | II |
Anwendungen & Verwendung
Verwenden
Vinyl Chloroformate was used to prepare analogues of the Nicotinic Acetylcholine Receptor Agonist (±)-UB-165. It was also used to synthesize possible antitumor agents such as paclitaxel-2''-carbonates and N-carbamyl triazenes.