Grundinformationen
- Standard-SMILES
O=C1C=CC(=O)O1- InChIKey
FPYJFEHAWHCUMM-UHFFFAOYSA-N- Summenformel
- C4H2O3
- Durchschnittliche Molmasse
- 98,06 g/mol
- Monoisotopische Masse
- 98,00039392
Namen und Bezeichner
- Bevorzugter Name
- Maleic Anhydride
- IUPAC
- furan-2,5-dione
- Lokaler Name
- Maleinsäureanhydrid
- Englischer Name
- Maleic anhydride
- Summenformel
- C4H2O3
- Molmasse
- 98.06
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
108-31-6、184288-31-1- PubChem CID
- 7923
- DTXSID
DTXSID7024166- ChEMBL
CHEMBL374159- ChEBI
CHEBI:474859- UNII
- V5877ZJZ25
- EC Number
- 203-571-6、606-024-3
- Nikkaji
- J2.419H
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- -0,1
- Polarare Oberfläche (TPSA)
- 43,4 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 3
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 7
- Formalladung
- 0
- Komplexität
- 129
Physikochemische Eigenschaften
- Schmelzpunkt
- 51 · 51-56 °C (lit.)
- Siedepunkt
- 200 °C · 200 °C (lit.)
- Dichte
- 1.48 · 1.48
- Dampfdichte
- 3.4 · 3.4 (vs air)
- Dampfdruck
- 0.16 mm · 0.16 mm Hg ( 20 °C)
- Brechungsindex
- 1.4688 · 1.4688 (estimate)
- Flammpunkt
- 218 °F · 218 °F
- storage temp.
- 30 °C · Store below +30°C.
- Löslichkeit
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- pka
- 0 · 0[at 20 ℃]
- Aggregatzustand
- powder
- Farbe
- White
- PH
- 0.8 · 0.8 (550g/l, H2O, 20℃)Hydrolysis
- Geruch (Odor)
- Mild acrid odor.
- Explosionsgrenze
- 1.4 · 1.4-7.1%(V)
- Wasserlöslichkeit
- 79 g/100 · 79 g/100 mL (25 ºC)
- Merck
- 14 · 14,5704
- BRN
- 106909 · 106909
- Henry's Law Constant
- (atmm3/mol): Not applicable - reacts with water
- Dielectric constant
- 51 · 51.0(60℃)
- Stabilität
- Stable. Combustible. Incompatible with water, strong oxidizing agents, alkali metals, strong bases, amines, most common metals, polymerization catalysts and accelerators.
- Kosmetik-Inhaltsstoffe Funktionen
- FILM FORMING
- InChI
- 1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
- InChIKey
- FPYJFEHAWHCUMM-UHFFFAOYSA-N
- SMILES
- O=C1OC(=O)C=C1
- LogP
- -2.61 at · -2.61 at 20℃
- CAS Datenbank
- 108 · 108-31-6(CAS DataBase Reference)
- NIST chemische Informationen
- 2 · 2,5-Furandione(108-31-6)
- EPA chemische Informationen
- Maleic anhydride (108-31-6)
Sicherheit und Regulatorisches
Sicherheitsdaten
- F
- 21
- OEB
- C
- OEL
- TWA: 1 mg/m3 (0.25 ppm)
- wgk
- 1
- IDLA
- 10 mg/m3
- tsca
- TSCA listed
- ridadr
- UN 2215 8/PG III (MALEIC ANHYDRIDE, MOLTEN)
- hs_code
- 2917 14 00
- RTECS-Nr.
- ON3675000
- risk_code
- 22-34-42/43
- Toxizität
- LD50 orally in Rabbit: 1090 mg/kg LD50 dermal Rabbit 2620 mg/kg
- hazard_code
- C
- safety_code
- 22-26-36/37/39-45
- hazard_class
- 8
- packing_group
- III
- Speicherklasse
- 6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
- Giftige Stoffe Daten
- 108-31-6(Hazardous Substances Data)
- Hazard Classifications
- Acute Tox. 4 OralEye Dam. 1Resp. Sens. 1Skin Corr. 1BSkin Sens. 1ASTOT RE 1 Inhalation
- Selbstentzündungstemperatur
- 870 °F
Chemie und Industrie
Anwendungen
BeschreibungMaleic Anhydride (MAN) is an organic compound with the chemical formula C4H203. It is the acid anhydride of maleic acid and in its pure state it is a colourless or white solid with an acrid odour. Maleic anhydride is truly a remarkable molecule in that it possesses two types of chemical functionality making it uniquely useful in chemical synthesis and applications.Maleic Anhydride is a multifunctional chemical intermediate with applications in several fields of chemical industry. Its major end use is as feedstock in the production of unsaturated polyester resins (UPR).These resins are used both in glass-reinforced and in unreinforced applications. The UPR end uses includes a wide range of applications in construction, marine and automobile industries.
VerwendenMaleic Anhydride is heterocyclic compound used in the manufacture of unsaturated polyester resins. It has a wide range of other applications; it is used in synthetic tensides, insecticides, herbicides and fungicides.
Darstellung
synthetischeTo a flask equipped with a Dean-Stark trap, condenser, and mechanical stirrer is added 116 gm (1.0 mole) of maleic acid and 120 ml of tetrachloroethane. The contents are heated, the water (18 ml, 1.0 mole) distilled off as the azeotrope, and the residue distilled under reduced pressure to afford 87.7 gm (89.5%) of the anhydride, b.p. 82-84°C (15 mm), m.p. 53°C. The residue remaining in the flask consists of about 10 gm of fumaric acid, m.p. 287°C. Fumaric and maleic acids both give maleic anhydride on heating. Fumaric acid must first be heated to a higher temperature to effect its conversion to maleic acid prior to its dehydration.
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Ergänzende Hinweise
DefinitionChEBI: Maleic anhydride is a cyclic dicarboxylic anhydride that is the cyclic anhydride of maleic acid. It has a role as an allergen. It is a cyclic dicarboxylic anhydride and a member of furans.
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