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3,6,9-Trioxaundecamethylendimethacrylat

Tetraethylene glycol, dimethacrylate

HCID 7980
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TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
109-17-1
Standard-SMILES
C=C(C)C(=O)OCCOCCOCCOCCOC(=O)C(=C)C
InChIKey
LTHJXDSHSVNJKG-UHFFFAOYSA-N
Summenformel
C16H26O7
Durchschnittliche Molmasse
330,37 g/mol
Monoisotopische Masse
330,16785317

Überblick

Based on available data, the CIR Expert Panel concluded that...PEG-4 Dimethacrylate is safe as used in nail enhancement products when skin contact is avoided. Products containing these ingredients should be accompanied with directions to avoid skin contact, because of the sensitizing potential of Methacrylates.

Namen und Bezeichner

Bevorzugter Name
Tetraethylene glycol, dimethacrylate
IUPAC
2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate
Lokaler Name
3,6,9-Trioxaundecamethylendimethacrylat
Englischer Name
Tetraethylene glycol dimethacrylate
Summenformel
C16H26O7
Molmasse
330.37

Namen und Synonyme

Tetraethylene glycol dimethacrylate109-17-1TETRAETHYLENEGLYCOL DIMETHACRYLATETe EGDMATGM 4Tetraethylene glycol, dimethacrylateSR 209Methacrylic acid, oxybis(ethyleneoxyethylene) esterDTXSID60445152-Propenoic acid, 2-methyl-, oxybis(2,1-ethanediyloxy-2,1-ethanediyl) esterMethacrylic acid, diester with tetraethylene glycolCT038EQF54
Weitere Namen anzeigen
PEG hydrogeltgm4sr209MACA-PEG4-MACATEGdimethacrylatPEG-4 DIMETHACRYLATE
NSC-84253DTXCID4024515teegdmaRefChem:897019203-653-1((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)PEG bismethacrylate3,6,9-Trioxaundecamethylene dimethacrylate

Datenbank-Bezeichner

CAS
109-17-1

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,5
Polarare Oberfläche (TPSA)
80,3 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
7
Frei drehbare Bindungen
16
Schwere Atome
23
Formalladung
0
Komplexität
354

Experimentelle und physikochemische Eigenschaften

PolymersPlastics & Rubber -> (Meth)acrylates
CosmeticsCosmetic ingredients (PEG-4 Dimethacrylate) -> CIR (Cosmetic Ingredient Review)
Physical Description · 2 Einträge

Liquid

Light brown viscous liquid; [Aldrich MSDS]

Collision Cross Section171.2 Ų [M+H]+ [CCS Type: DT; Buffer gas: N2; Ionization: APCI+; Dataset: TOXCAST; Source Identifier: DTXSID6044515]

Physikochemische Eigenschaften

Schmelzpunkt
220 ℃ · 220℃
Siedepunkt
220 °C · 220°C
Dichte
1.082 g/mL · 1.082 g/mL at 20 °C(lit.)
Dampfdruck
0 Pa · 0Pa at 20℃
Brechungsindex
20 · n20/D 1.463
Flammpunkt
196 °C · 196°C
storage temp.
-20 °C · -20°C

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 14.3% (5 of 35) of reports.

Warning

H315 (80%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 35 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: 2-Propenoic acid, 2-methyl-, oxybis(2,1-ethanediyloxy-2,1-ethanediyl) ester

2-Propenoic acid, 2-methyl-, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: 3,6,9-trioxaundecamethylene dimethacrylate (EC: 203-653-1)

2-Propenoic acid, 2-methyl-, oxybis(2,1-ethanediyloxy-2,1-ethanediyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards SummaryAllergic contact dermatitis reported in dental technicians; [Kanerva, p. 1187] May cause irritation; [Aldrich MSDS]
Hazard Classes and CategoriesSkin Irrit. 2 (80%)

Toxikologische Informationen

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

CIR ingredient: PEG-4 Dimethacrylate

Plastic Composites Manufacturing [Category: Industry]

U.S. Production2023: 50,000 - <250,000 lb
Consumer UsesMonomers
Industry UsesMonomers
General Manufacturing Information · 2 Einträge

Plastics Material and Resin Manufacturing

2-Propenoic acid, 2-methyl-, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester: ACTIVE

Anwendungen · 2 Einträge

BeschreibungTetraethylene glycol dimethacrylate is a crosslinking agent of acrylic resins, employed to optimize the dilution of high-viscosity monomers and to link together the macromolecules costituting the polymer, to make their three-dimentional structure more rigid. Occupational dermatitis was reported in a dental technician.

VerwendenPlasticizer.

Anbieter100 Anbieter

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梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
PubChem CID
7980
DTXSID
DTXSID6044515
ChEMBL
CHEMBL3184138
UNII
CT038EQF54
EC Number
203-653-1
Nikkaji
J143.896D
Löslichkeit
soluble in Methanol
Aggregatzustand
clear liquid
Farbe
Colorless to Almost colorless
Wasserlöslichkeit
12.6 g/L · 12.6g/L at 20℃
BRN
1803537 · 1803537
Kosmetik-Inhaltsstoffe Funktionen
FILM FORMINGBINDING
InChI
1S/C16H26O7/c1-13(2)15(17)22-11-9-20-7-5-19-6-8-21-10-12-23-16(18)14(3)4/h1,3,5-12H2,2,4H3
InChIKey
LTHJXDSHSVNJKG-UHFFFAOYSA-N
SMILES
C=C(C)C(OCCOCCOCCOCCOC(C(C)=C)=O)=O
LogP
2.04 at · 2.04 at 40℃
CAS Datenbank
109 · 109-17-1(CAS DataBase Reference)
EPA chemische Informationen
Tetraethylene glycol dimethacrylate (109-17-1)
Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Toxicity Summary · 2 Einträge

Based on available data, the CIR Expert Panel concluded that...PEG-4 Dimethacrylate is safe as used in nail enhancement products when skin contact is avoided. Products containing these ingredients should be accompanied with directions to avoid skin contact, because of the sensitizing potential of Methacrylates.

Safe for use in cosmetics, with qualifications

Sicherheitsdaten

wgk
1
tsca
TSCA listed
ridadr
UN 3082 9/PG 3
hs_code
2916.14.2050
RTECS-Nr.
OZ4000000
Toxizität
LD50 skin in rabbit: > 3gm/kg
safety_code
23-24/25
Speicherklasse
10 - Combustible liquids
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