StartseiteMCPWorkbenchSkills
StartseiteWorkbenchBenachrichtigungenMein Bereich
llms.txt · MCP-AnleitungDatenschutz · Nutzungsbedingungen · Supportv1.8.0
  1. Startseite
  2. /Verbindung

Divinylether

Vinyl ether

HCID 8024
Neue NotizNeue ReaktionAnfrage stellen
Druckvorschau
GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
109-93-3
Standard-SMILES
C=COC=C
InChIKey
QYKIQEUNHZKYBP-UHFFFAOYSA-N
Summenformel
C4H6O
Durchschnittliche Molmasse
70,09 g/mol
Monoisotopische Masse
70,04186481

Überblick

Divinyl ether, stabilized appears as a clear colorless liquid with a characteristic odor. Less dense than water. Vapors heavier than air. Toxic by inhalation.

Namen und Bezeichner

Bevorzugter Name
Vinyl ether
IUPAC
ethenoxyethene
Lokaler Name
Divinylether
Englischer Name
Vinyl ether
Summenformel
C4H6O
Molmasse
70.09

Namen und Synonyme

Vinyl etherDIVINYL ETHERDivinyl oxide109-93-3EthenyloxyetheneEther, divinyl(ethenyloxy)ethene2H2T044E11ether, vinylRefChem:194318203-720-5ethenoxyethene
Weitere Namen anzeigen
(vinyloxy)ethenevinyloxyethylene1,1'-oxybisethene
VinetherVinidylVinydanVinestheneVinesthesinVinethenVinetheneEthene, 1,1'-oxybis-

Datenbank-Bezeichner

CAS
109-93-3
PubChem CID
8024
DTXSID
DTXSID5074555
ChEMBL
CHEMBL2105883
ChEBI
CHEBI:81293
UNII
2H2T044E11
EC Number
203-720-5
Nikkaji
J2.441D

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,3
Polarare Oberfläche (TPSA)
9,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
2
Schwere Atome
5
Formalladung
0
Komplexität
32,9

Experimentelle und physikochemische Eigenschaften

Chemical ClassesFlammable agents - 4th degree
PolymersPlastics & Rubber -> Other Monomers
SpringerMaterials PropertiesSchoenflies notation
Flash Pointless than -22 °F (NFPA, 2010)
Physical Description · 2 Einträge

Divinyl ether, stabilized appears as a clear colorless liquid with a characteristic odor. Less dense than water. Vapors heavier than air. Toxic by inhalation.

Colorless liquid; [CAMEO]

Physikochemische Eigenschaften

Schmelzpunkt
-101.1 °C · -101.1°C
Siedepunkt
28.4 ° · bp 28.4°
Dichte
2020 · d2020 0.774; d420 0.773
Brechungsindex
20 · nD20 1.3989
Wasserlöslichkeit
5.25 g/L · 5.25g/L(37 ºC)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Gefahrenhinweise

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelFlammable Liquid
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:

CAUTION: Petroleum crude oil (UN1267) may contain TOXIC hydrogen sulphide gas.

Hazards SummaryMay irritate or burn skin and eyes; Inhalation can cause dizziness and suffocation; [CAMEO] Divinyl ether, stabilized (UN1167) has warning of explosive polymerization. [ERG 2016] See Ethyl vinyl ether.
DOT ID and Guide1167 128P
Reactive GroupEthers
Reactivity AlertsHighly Flammable
Reactivity Profile · 1 Eintrag

Ethers, such as DIVINYL ETHER, can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert. It is miscible with alcohol, acetone, chloroform and ether and must be protected from light [Hawley].

Chemie und Industrie

Pharmakologische Informationen

ATC Code · 2 Einträge

N - Nervous system

QN - Nervous system

MeSH Pharmacological Classification · 1 Eintrag

Agents capable of inducing a total or partial loss of sensation, especially tactile sensation and pain. They may act to induce general ANESTHESIA, in which an unconscious state is achieved, or may act locally to induce numbness or lack of sensation at a targeted site.

Anwendungen

VerwendenVinyl ether is used as an anesthetic and inorganic synthesis.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

ethenylsulfanylethene2-Iodoethyl etherEthylene glycol divinyl ether, 962,2'-Dichlor-diethylether1,1-Diethoxyethan(2-Chlorethoxy)ethen

Nachgelagerte Produkte

Butylvinyletheralcohol polyoxyethylene ether phosphoric monoesterhigh-temperature leveling agent FZ-802oil agent for synthetic fiber

Zugehörige Reaktionen

48
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 31361
HRID 31361als Eduktuspto-grants-2008_09
Reaktionsgleichung von HRID 57437
HRID 57437als Eduktuspto-grants-2016_09
Reaktionsgleichung von HRID 161581
HRID 161581als EduktTraining data from https://doi.org/10.1039/C8SC04228D (9/10)
Reaktionsgleichung von HRID 217418
HRID 217418als Eduktuspto-grants-2012_06
Reaktionsgleichung von HRID 242760
HRID 242760als Eduktuspto-grants-2014_02
Reaktionsgleichung von HRID 267666
HRID 267666als Eduktuspto-grants-1976_03
Reaktionsgleichung von HRID 304907
HRID 304907als EduktTraining data from https://doi.org/10.1039/C8SC04228D (8/10)
Reaktionsgleichung von HRID 313207
HRID 313207als EduktTraining data from https://doi.org/10.1039/C8SC04228D (8/10)
Seite 1 von 6

Notizen zur Verbindung

Wird geladen…

Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Weitere Aktionen
Neue NotizNeue ReaktionAnfrage stellen
Henry's Law Constant
5.4 · 5.4×10-4 mol/(m3Pa) at 25℃, Steward et al. (1973)
Dielectric constant
3.9 · 3.9(20℃)
EPA chemische Informationen
1 · Ethene, 1,1'-oxybis- (109-93-3)
DOT Hazard Classification · 4 Einträge

Divinyl ether, stabilized

UN1167

Class 3 Flammable and combustible liquid (49 eCFR § 173.120)

PG I: the degree of danger presented by the material is great

Air and Water ReactionsHighly flammable. Slightly soluble in water. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164].
Peroxide Forming Chemical · 4 Einträge

Divinyl ether

D*: Other compounds that may form peroxides

Bretherick's

Anon., Chemist & Druggist, 1947, 157, 258

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:

Immediate precautionary measure

Personal Protective Equipment (PPE)Excerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible); polymerization hazard]:
Emergency Response Planning GuidelinesCAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.

Toxikologische Informationen

Adverse EffectsNeurotoxin - Acute solvent syndrome

Sicherheitsdaten

ridadr
UN 1167 (DIVINYL ETHER, STABILIZED)
Toxizität
LC50 (3 hr in air) in mice, rats (mg/l): 146.8, 386.5 (Molitor)
hazard_class
3
packing_group
I
perfluorinated sulfonic acid resin
detergent 801
2-Methyl-1,3-dioxolan
(3Z)-4-Ethoxy-1,1,1-trifluoro-3-buten-2-one