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Isopropyldiphenylphosphin
NSC 244305 · Einecs 228-902-1 · Isopropyldiphenylphosphin · I-PROPYLDIPHENYLPHOSPHINE · Isopropyldiphenylphosphine · DIPHENYL-ISO-PROPYLPHOSPHINE · Isopropyl(biphenyl)phosphine · i-Propyldiphenylphosphine,99%
Identifikatoren & physikalische Daten
| CAS No. | 6372-40-3 |
|---|---|
| Summenformel | C15H17P |
| Durchschnittliche Molmasse | 228,27 g/mol |
| Monoisotopische Masse | 228,10678717 g/mol |
| SMILES | CC(C)P(c1ccccc1)c1ccccc1 |
| InChIKey | LLZAIAIZAVMQIG-UHFFFAOYSA-N |
| PubChem CID | 80754 |
| EC No. | 228-902-1 |
| DTXSID | DTXSID50213143 |
| Lokaler Name | Isopropyldiphenylphosphin |
Chemische & physikalische Eigenschaften
| XLogP | 3,9 |
|---|---|
| Polarare Oberfläche (TPSA) | 0 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 16 |
| Formalladung | 0 |
| Komplexität | 170 |
| Schmelzpunkt | 40-43 °C (lit.) |
| Siedepunkt | 165 °C/11 mmHg (lit.) |
| Dichte | 0.861 |
| Flammpunkt | >230 °F |
| Lagerbedingungen | under inert gas (nitrogen or Argon) at 2-8°C |
| Aggregatzustand | solid |
| Farbe | White or Colorless to Almost white or Almost colorless |
| InChI | InChI=1S/C15H17P/c1-13(2)16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-13H,1-2H3 |
| InChIKey | LLZAIAIZAVMQIG-UHFFFAOYSA-N |
| SMILES | P(C(C)C)(C1=CC=CC=C1)C1=CC=CC=C1 |
| CAS Datenbank | 6372-40-3(CAS DataBase Reference) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Hazard Classes and Categories | Skin Irrit. 2 (100%) |
| Wassergefährdungsklasse (WGK) | 3 |
| Zollcode | 2931.90.6000 |
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-37/39 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
Anwendungen & Verwendung
Verwenden
Catalyst in:Nickel/Lewis acid-catalyzed aryl- and alkenylcyanation of unsaturated bondsNickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of AlkynesMethoxycarbonylation reactions (palladium complex)Decarboxylative cross-coupling in the presence of palladiumAsymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonitesHydroesterification of vinylarenes in complex with palladiumLigand precatalyst for room-temperature Heck coupling reactions