3,4-Dihydro-2H-pyran

HCID 8080CAS 110-87-2

Grundinformationen

Standard-SMILES
C1=COCCC1
InChIKey
BUDQDWGNQVEFAC-UHFFFAOYSA-N
Summenformel
C5H8O
Durchschnittliche Molmasse
84,12 g/mol
Monoisotopische Masse
84,05751488

Überblick

Dihydro-2h-pyran appears as a clear colorless liquid with an ethereal odor. Less dense than water. Vapors heavier than air.

Namen und Bezeichner

Bevorzugter Name
3,4-dihydro-2H-pyran
IUPAC
3,4-dihydro-2H-pyran
Lokaler Name
3,4-Dihydro-2H-pyran
Englischer Name
3,4-Dihydro-2H-pyran
Summenformel
C5H8O
Molmasse
84.12

Namen und Synonyme

3,4-Dihydro-2H-pyran110-87-2DIHYDROPYRAN3,4-Dihydropyran2,3-Dihydro-4H-pyran2H-3,4-Dihydropyran5,6-Dihydro-4H-pyran2H-Pyran, 3,4-dihydro-delta2-DihydropyranPyran, dihydro-DTXSID6041426T6V9N71IHX
Weitere Namen anzeigen
DHP3,4-Dihydro-2H-pyraneDIHYDROPYRANE3,4-Dihydro-2-pyran3,4-dihydro-2h-pyra
NSC-57860NSC-73472DTXCID4021426RefChem:910852,3-DIHYDRO-GAMMA-PYRAN203-810-4Dihydro-2H-pyran2,3-Dihydropyran

Datenbank-Bezeichner

CAS
110-87-2、25512-65-6、3174-74-1
PubChem CID
8080
DTXSID
DTXSID6041426
ChEMBL
CHEMBL3184439
UNII
T6V9N71IHX
EC Number
203-810-4
Nikkaji
J43.463I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
0,7
Polarare Oberfläche (TPSA)
9,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
6

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Other Classes -> Ethers, Other

Flammable agents - 3rd degree

SpringerMaterials PropertiesCoriolis coupling
LogP0.69
Density0.922 @ 19°C
Flash Point0 °F (NFPA, 2010)
Physical Description · 3 Einträge

Dihydro-2h-pyran appears as a clear colorless liquid with an ethereal odor. Less dense than water. Vapors heavier than air.

Liquid

Clear colorless liquid with an ethereal odor; [CAMEO] Unpleasant odor; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
-70 °C · -70 °C (lit.)
Siedepunkt
86 °C · 86 °C (lit.)
Dichte
0.922 g/mL · 0.922 g/mL at 25 °C (lit.)
Dampfdichte
2.9 · 2.9 (vs air)
Dampfdruck
77.8 hPa · 77.8 hPa (20 °C)
Brechungsindex
20 · n20/D 1.440(lit.)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P272, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 180 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: 2H-Pyran, 3,4-dihydro-

2H-Pyran, 3,4-dihydro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2H-Pyran, 3,4-dihydro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 29-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/12042

2H-Pyran, 3,4-dihydro-: HSNO Approval: HSR001129 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· Inhalation or contact with material may irritate or burn skin and eyes.

Hazards SummaryA skin and strong eye irritant; [Alfa Aesar MSDS]
DOT ID and Guide2376 127

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

Immediate precautionary measure

Toxikologische Informationen

Toxicity DataLC50 (rat) > 10,700 mg/m3/4hr

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 2376
hs_code
29329995
RTECS-Nr.
UP7700000
risk_code
11-36/37/38-36/38-19

Chemie und Industrie

Verwendung und Herstellung

UsesPermitted for use as an inert ingredient in non-food pesticide products; [EPA] Used in organic syntheses; [REPROTOX]
U.S. Production2023: 75,000 - <500,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

All Other Basic Organic Chemical Manufacturing

2H-Pyran, 3,4-dihydro-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenWidely used hydroxyl-protecting reagent3,4-Dihydro-2H-pyran is used as a hydroxyl-protecting reagent in organic synthesis. It acts as an intermediate in synthetic chemistry. It is used to protect various reactive functional groups. It is involved in the polymerization reaction either alone or with unsaturated compound and finds application in polymer industries. Further, it is employed in the preparation of bicyclic compounds of epoxide-fused, halo compounds and allenic alcohols.

Anbieter50 Anbieter

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