Tetramethylhexamethylenediamine (HCID 8097)

Überblick

See also: Hexadimethrine Bromide (monomer of); Hexadimethrine chloride (monomer of); Hexadimethrine (monomer of).

Namen und Bezeichner

Bevorzugter Name: Tetramethylhexamethylenediamine
IUPAC: N,N,N',N'-tetramethylhexane-1,6-diamine
Lokaler Name: N,N,N',N'-Tetramethylhexamethylen-diamin
Englischer Name: N,N,N',N'-Tetramethyl-1,6-hexanediamine
Summenformel: C10H24N2
Molmasse: 172.31

Namen und Synonyme

1,6-Bis(dimethylamino)hexaneHexamethylenebis(dimethylamine)tetramethylhexamethylenediamine1,6-HEXANEDIAMINE, N,N,N',N'-TETRAMETHYL-Toyocat MRKoolizer 1Minico TMHDNIAX catalyst C-210U 1000 (amine)N,N,N',N'-TetramethylhexamethylenediamineEINECS 203-842-9U 1000

Weitere Namen anzeigen

TMHDTMHDAN1,N1,N6,N6-TetraMethylhexane-1,6-diaMineN,N,N,N-Tetramethyl-1,6-hexanediamine6-hexanediamineu1000TMHMDAkoolizer1Ambap3162toyocatmr

UNII-7D0T53S99VBRN 1738567AI3-26634N,N,N',N'-Tetramethylhexamethylene diamine7D0T53S99VU-CAT 1000EC 203-842-94-04-00-01322 (Beilstein Handbook Reference)

Datenbank-Bezeichner

CAS: 111-18-2
PubChem CID: 8097
DTXSID: DTXSID5033701
ChEMBL: CHEMBL118765
UNII: 7D0T53S99V
EC Number: 203-842-9
Nikkaji: J26.197A

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 1,7
Polarare Oberfläche (TPSA): 6,5 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 2
Frei drehbare Bindungen: 7
Schwere Atome: 12
Formalladung: 0
Komplexität: 77,8

Experimentelle und physikochemische Eigenschaften

Physical DescriptionLiquid

Physikochemische Eigenschaften

Schmelzpunkt: -46 °C · -46 °C
Siedepunkt: 209 · 209-210 °C(lit.)
Dichte: 0.806 g/mL · 0.806 g/mL at 25 °C(lit.)
Dampfdruck: 12.4 Pa · 12.4Pa at 20℃
Brechungsindex: 20 · n20/D 1.4359(lit.)
Flammpunkt: 165 °F · 165 °F
storage temp.: Sealed in dry,Room Temperature
Löslichkeit: miscible
Aggregatzustand: Liquid
pka: 10.07 · 10.07±0.28(Predicted)
Farbe: Clear colorless to yellow
Wasserlöslichkeit: miscible
LogP: 1.99 at · 1.99 at 23℃
CAS Datenbank: 111 · 111-18-2(CAS DataBase Reference)
NIST chemische Informationen: (CH3)2N(CH2)6N(CH3)2(111-18-2)
EPA chemische Informationen: -1 · N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H301+H311+H331 (23.9%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 264 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H227: Combustible liquid [Warning Flammable liquids]

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: 1,6-Hexanediamine, N,N,N',N'-tetramethyl-

1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 13-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/11920

1,6-Hexanediamine, N,N,N',N'-tetramethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and Categories · 2 Einträge

Acute Tox. 3 (88.3%)

Flammable liquids - Category 4

Sicherheitsdaten

wgk: 1
tsca: TSCA listed
ridadr: UN 3390 6.1/PG 1
hs_code: 29212900
RTECS-Nr.: MO1370000
risk_code: 22-24-34-23/24
hazard_code: T
safety_code: 26-36/37/39-45
hazard_class: 8
packing_group: III

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 29,063 lb

Industry UsesCatalyst

General Manufacturing Information · 2 Einträge

All Other Basic Organic Chemical Manufacturing

1,6-Hexanediamine, N1,N1,N6,N6-tetramethyl-: ACTIVE

Anwendungen

VerwendenN,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.

Darstellung

synthetischeN,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.