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Butylvinylether
BUTYL VINYL ETHER · VINYL BUTYL ETHER · Bve · 1-(ETHENYLOXY)BUTANE · Polyvinox · butoxy-ethene · ether,butylvinyl · (BUTYLOXY)ETHYLENE
Identifikatoren & physikalische Daten
| CAS No. | 111-34-2 |
|---|---|
| Summenformel | C6H12O |
| Durchschnittliche Molmasse | 100,16 g/mol |
| Monoisotopische Masse | 100,088815 g/mol |
| SMILES | C=COCCCC |
| InChIKey | UZKWTJUDCOPSNM-UHFFFAOYSA-N |
| PubChem CID | 8108 |
| ChEMBL | CHEMBL3561125 |
| EC No. | 203-860-7 |
| DTXSID | DTXSID5051575 |
| Lokaler Name | Butylvinylether |
Chemische & physikalische Eigenschaften
| XLogP | 2,1 |
|---|---|
| Polarare Oberfläche (TPSA) | 9,2 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 4 |
| Schwere Atome | 7 |
| Formalladung | 0 |
| Komplexität | 41 |
| Dichte | 0.7888 at 20 °C/20 °CBulk density: 7.45 lb/gal at 20 °C0.774 g/mL at 25 °C(lit.) |
| Color/Form | Liquid |
| Löslichkeit | Sol in alc and etherSol in acetone, benzeneWater solubility of 3,000 mg/lVery sol in ethyl alcohol, acetonemiscible in ethyl ether3g/l3 g/L (20 ºC) |
| Flammpunkt | 15 °F (NFPA, 2010)-9 °C (Open cup) |
| Siedepunkt | 94 °C94 °C(lit.) |
| Decomposition | When heated to decomposition it emits acrid smoke and irritating fumes. |
| Schmelzpunkt | -92 °C−92 °C(lit.) |
| Dampfdichte | 3.45 (Air = 1)3.5 (vs air) |
| Dampfdruck | 49.1 [mmHg]49 mm Hg at 25 °C /from experimentally derived coefficients/42 mm Hg ( 20 °C) |
| Brechungsindex | Index of refraction: 1.4026 at 20 °Cn20/D 1.400(lit.) |
| Physical Description | Butyl vinyl ether, stabilized appears as a liquid. Less dense than water. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.Slightly soluble in water[Hawley] |
| Kovats Retention Index | 695687671679858 |
| Lagerbedingungen | 2-8°C |
| Aggregatzustand | Liquid |
| Farbe | Clear |
| Explosionsgrenze | 1.2-8.6%(V) |
| Spezifische Wärmekapazität | Cp(liquid): 2.32 J/(g·K), at 25℃ |
| BRN | 1560217 |
| Henry-Konstante | 4.6×10-3 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) |
| InChI | 1S/C6H12O/c1-3-5-6-7-4-2/h4H,2-3,5-6H2,1H3 |
| InChIKey | UZKWTJUDCOPSNM-UHFFFAOYSA-N |
| SMILES | CCCCOC=C |
| LogP (Verteilungskoeffizient) | 3.15 at 20℃ |
| CAS Datenbank | 111-34-2(CAS DataBase Reference) |
| NIST chemische Informationen | Butane, 1-(ethenyloxy)-(111-34-2) |
| EPA chemische Informationen | Butyl vinyl ether (111-34-2) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]H315 (74%): Causes skin irritation [Warning Skin corrosion/irritation]H317 (70.7%): May cause an allergic skin reaction [Warning Sensitization, Skin]P210, P233, P240, P241, P242, P243, P261, P264, P272, P280, P302+P352, P303+P361+P353, P321, P332+P317, P333+P317, P362+P364, P370+P378, P403+P235, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 150 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Regulatorische Informationen | Chemical: Butane, 1-(ethenyloxy)-Status: Active Update: 07-01-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/33141Status: Active Update: 21-09-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/16525Butane, 1-(ethenyloxy)-: HSNO Approval: HSR001104 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Flammable Liquid |
| Brandgefahren | Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)polymerization hazard]:HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. CAUTION: Ethanol (UN1170) can burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids will float on water. (ERG, 2024) |
Anwendungen & Verwendung
Verwenden
Synthesis, copolymerization.