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tert-Butylhydrazinmonohydrochlorid
RARECHEM AQ A1 0040 · T-Butylhydrazine HCL · tert-Butylhydrazine Hcl · 1-(Tert-butyl)hydrazineHCl · tert-butylhydraziniumchloride · T-BUTYLHYDRAZINE HYDROCHLORIDE · ert-Butylhydrazinehydrochloride · tert-butyl-hydrazinhydrochloride
Identifikatoren & physikalische Daten
| CAS No. | 7400-27-3 |
|---|---|
| Summenformel | C4H12N2.ClH |
| Durchschnittliche Molmasse | 124,61 g/mol |
| Monoisotopische Masse | 124,0767261 g/mol |
| SMILES | CC(C)(C)NN.Cl |
| InChIKey | DDPWVABNMBRBFI-UHFFFAOYSA-N |
| PubChem CID | 81889 |
| EC No. | 231-001-6 |
| DTXSID | DTXSID1064661 |
| Lokaler Name | tert-Butylhydrazinmonohydrochlorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 38,1 |
|---|---|
| H-Brücken-Donoren | 3 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 7 |
| Formalladung | 0 |
| Komplexität | 35,3 |
| Stoffklassen | Nitrogen Compounds -> Hydrazines |
| Physical Description | Hygroscopic crystalline powder[Alfa Aesar MSDS] |
| Schmelzpunkt | 191-194 °C(lit.) |
| Lagerbedingungen | Keep in dark place,Sealed in dry,Room Temperature |
| Löslichkeit | DMSO, MethanolSolubility in water (almost transparency). Soluble in DMSO and methanol. |
| Aggregatzustand | Crystals or Crystalline Powder |
| Farbe | White |
| BRN | 3651224 |
| InChI | InChI=1S/C4H12N2.ClH/c1-4(2,3)6-5/h6H,5H2,1-3H31H |
| InChIKey | DDPWVABNMBRBFI-UHFFFAOYSA-N |
| SMILES | C(C)(C)(C)NN.Cl |
| CAS Datenbank | 7400-27-3(CAS DataBase Reference) |
| EPA chemische Informationen | Hydrazine, (1,1-dimethylethyl)-, monohydrochloride (7400-27-3) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302 (56.4%): Harmful if swallowed [Warning Acute toxicity, oral]P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 133 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Hydrazine, (1,1-dimethylethyl)-, monohydrochlorideStatus: Active Update: 09-12-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/12290Hydrazine, (1,1-dimethylethyl)-, monohydrochloride: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | A mild skin irritant[RTECS] A skin and strong eye irritantToxic by ingestion[Alfa Aesar MSDS] See 1,2-Dimethylhydrazine dihydrochloride. |
| Hazard Classes and Categories | Acute Tox. 4 (56.4%) |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | 2811 |
| Zollcode | 29280000 |
| RTECS-Nr. | MV2841000 |
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| hazard_note | Irritant |
| Sicherheitshinweise (S) | 26-36-24/25 |
| Verpackungsgruppe | III |
| Lagerklasse | 11 - Combustible Solids |
Anwendungen & Verwendung
Verwenden
It is used in organic synthesis for aromatic nucleophilic N-N exchange reaction. tert-Butylhydrazine Hydrochloride is also used in the preparation of insect growth regulator. tert-Butylhydrazine hydrochloride was used in the synthesis of diphosphinohydrazines, 5-amino-1-tert-butyl-3-(p-chlorophenyl)-4-cyanopyrazole and 1,3,4,5-tetrasubstituted pyrazole derivatives.