Diethylene glycol dibutyl ether

HCID 8210CAS 112-73-2

Grundinformationen

Standard-SMILES
CCCCOCCOCCOCCCC
InChIKey
KZVBBTZJMSWGTK-UHFFFAOYSA-N
Summenformel
C12H26O3
Durchschnittliche Molmasse
218,33 g/mol
Monoisotopische Masse
218,18819469

Namen und Bezeichner

Bevorzugter Name
Diethylene glycol dibutyl ether
IUPAC
1-[2-(2-butoxyethoxy)ethoxy]butane
Englischer Name
Diethylene Glycol Dibutyl Ether
Summenformel
C12H26O3
Molmasse
218.33

Namen und Synonyme

112-73-2DIETHYLENE GLYCOL DIBUTYL ETHERBis(2-butoxyethyl) etherDibutyl carbitolButyl diglyme5,8,11-TrioxapentadecaneEther, bis(butoxyethyl)2-Butoxyethyl etherDiethylene glycol di-n-butyl ether2,2'-Dibutoxyethyl etherButexEther, bis(2-butoxyethyl)
Weitere Namen anzeigen
Diethylene Glycol Di-n-butylDiethylene glycol diBIS(BUTOXYETHYL)ETHER
Dibutylether diethylenglykoluButane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-Diethyleneglycoldibutyl etherDTXSID8025046EINECS 204-001-9Dibutylether diethylenglykolu [Czech]F8P3DHG73ZBRN 1750713

Datenbank-Bezeichner

CAS
112-73-2
PubChem CID
8210
DTXSID
DTXSID8025046
ChEMBL
CHEMBL1485392
UNII
F8P3DHG73Z
EC Number
204-001-9
Nikkaji
J36.822I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,9
Polarare Oberfläche (TPSA)
27,7 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
12
Schwere Atome
15

Experimentelle und physikochemische Eigenschaften

Density · 2 Einträge

0.885 (USCG, 1999) - Less dense than water; will float

0.8853 @ 20°C

Solubilityless than 1 mg/mL at 72 °F (NTP, 1992)
Flash Point · 2 Einträge

245 °F (NTP, 1992)

245.0 °F [CAMEO] VP from ChemIDplus

Boiling Point · 2 Einträge

493 °F at 760 mmHg (NTP, 1992)

256 °C @760 [mm Hg]

Melting Point-76 °F (NTP, 1992)
Vapor Densitygreater than 1 (NTP, 1992) (Relative to Air)

Physikochemische Eigenschaften

Schmelzpunkt
-60 °C · -60 °C (lit.)
Siedepunkt
256 °C · 256 °C (lit.)
Dichte
0.885 g/mL · 0.885 g/mL at 25 °C (lit.)
Dampfdichte
1 · >1 (vs air)
Dampfdruck
0.01 mm · <0.01 mm Hg ( 20 °C)
Brechungsindex
20 · n20/D 1.423(lit.)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 3 Einträge

This chemical does not meet GHS hazard criteria for 94.6% (192 of 203) of all reports.

Not Classified;Reported as not meeting GHS hazard criteria by 192 of 203 companies (only 5.4% companies provided GHS information). For more detailed information, please visit ECHA C&L website.

Aggregated GHS information provided per 203 reports by companies from 7 notifications to the ECHA C&L Inventory.;Reported as not meeting GHS hazard criteria per 192 of 203 reports by companies.;There are 5 notifications provided by 11 of 203 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-07-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/5839

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsSpecial Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
Health HazardsMay be harmful by inhalation, ingestion and skin absorption. Causes eye and skin irritation. Material is irritating to mucous membrane and upper respiratory tract. (USCG, 1999)
Hazards SummaryOxidizes in air and may cause explosive peroxides; A skin and eye irritant; [CAMEO] See Monoglyme.
Reactive GroupEthers
Reactivity AlertsPeroxidizable Compound

Sicherheit und Schutzausrüstung

Fire FightingFire Extinguishing Agents: Water spray, dry chemical, alcohol foam. (USCG, 1999)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.;STORAGE PRECAUTIONS: You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)

Protective Action Criteria (PAC) · 3 Einträge

12 [ppm]

130 [ppm]

770 [ppm]

Personal Protective Equipment (PPE)Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. (USCG, 1999)

Toxikologische Informationen

Adverse EffectsNeurotoxin - Acute solvent syndrome

Regulatorische Informationen

Regulatory Information · 5 Einträge

Chemical: Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-07-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/5839

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: Does not have an individual approval but may be used under an appropriate group standard

Sicherheitsdaten

wgk
1
tsca
TSCA listed
hs_code
29091900
RTECS-Nr.
KN0350000
Toxizität
LD50 orally in Rabbit: 3900 mg/kg LD50 dermal Rabbit 3555 mg/kg
safety_code
23-24/25

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as a solvent with applications in coatings and inks, vinyl chloride dispersion, and uranium extraction; [Hawley]

Painting (Solvents) [Category: Paint]

U.S. Production2023: 131,154 lb;2022: 141,941 lb;2021: 66,002 lb;2020: 609,534 lb
Industry UsesAlloys;Solvent;Not Known or Reasonably Ascertainable;Corrosion inhibitor;Flux agent
General Manufacturing Information · 2 Einträge

Not Known or Reasonably Ascertainable;All Other Chemical Product and Preparation Manufacturing;Primary Metal Manufacturing

Butane, 1,1'-[oxybis(2,1-ethanediyloxy)]bis-: ACTIVE

Anwendungen

VerwendenButyl diglyme is used to extract gold from hydrochloric acid solutions containing other metals. Treatment of the diglyme extract with hydrogen or oxalic acid precipitates the ionic gold as gold powder.

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