Tribenzylphosphin

Phosphine, tris(phenylmethyl)-

HCID 82101CAS 7650-89-7

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Grundinformationen

Standard-SMILES: c1ccc(CP(Cc2ccccc2)Cc2ccccc2)cc1
InChIKey: IFXORIIYQORRMJ-UHFFFAOYSA-N
Summenformel: C21H21P
Durchschnittliche Molmasse: 304,4 g/mol
Monoisotopische Masse: 304,1380873

Namen und Bezeichner

Bevorzugter Name: Phosphine, tris(phenylmethyl)-
IUPAC: tribenzylphosphane
Lokaler Name: Tribenzylphosphin
Englischer Name: TRIBENZYLPHOSPHINE
Summenformel: C21H21P
Molmasse: 304.37

Namen und Synonyme

Tribenzylphosphine7650-89-7Phosphine, tris(phenylmethyl)-EINECS 231-608-6DTXSID9073385RefChem:861962DTXCID3047895231-608-6tribenzylphosphaneTribenzyl phosphineTRYMETHYL PHOSPHINEMFCD00014439

Weitere Namen anzeigen

TribenzylphoshineTrisbenzylphosphineTribenzylphosphine 98%TRIBENZYLPHOSPHINE,98%TRIBENZYLPHOSPHINE (TBZP)

Phosphine, tribenzyl-Tris(phenylmethyl)phosphineBn3PTribenzylphosphine, 97%Tribenzylphosphine, 98%(PhCH2)3PSCHEMBL196203HAA65089

Datenbank-Bezeichner

CAS: 7650-89-7
PubChem CID: 82101
DTXSID: DTXSID9073385
EC Number: 231-608-6
Nikkaji: J125.045K

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 4,4
Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 6
Schwere Atome: 22
Formalladung: 0
Komplexität: 235

Physikochemische Eigenschaften

Schmelzpunkt: 96 · 96-101 °C (lit.)
Siedepunkt: 183 · 183-185°C/0.2mm
Flammpunkt: 183 · 183-185°C/0.2mm
Aggregatzustand: Crystalline
Farbe: White
Wasserlöslichkeit: Insoluble in water.
BRN: 650179 · 650179
InChI: 1S/C21H21P/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2
InChIKey: IFXORIIYQORRMJ-UHFFFAOYSA-N
SMILES: C(P(Cc1ccccc1)Cc2ccccc2)c3ccccc3
CAS Datenbank: 7650 · 7650-89-7(CAS DataBase Reference)
EPA chemische Informationen: Phosphine, tris(phenylmethyl)- (7650-89-7)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 43 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesSkin Irrit. 2 (100%)

Sicherheitsdaten

F: 10-23
wgk: 3
tsca: TSCA listed
RTECS-Nr.: SZ3865000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26
Speicherklasse: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationPhosphine, tris(phenylmethyl)-: INACTIVE

Anwendungen · 1 Eintrag

VerwendenTribenzylphosphine is used as a co catalyst in preparation of coumarin derivatives via nickel-catalyzed cycloaddition, copolymerization reactions, Rh-catalyzed hydroformylation reactions, preparation of substituted allylamines by three-component coupling of alkynes, imines and organoboranes.