Trimethyl-2-propinylsilan

Trimethyl-2-propynylsilane

HCID 83378CAS 13361-64-3

Teilstruktursuche Ähnliche Strukturen suchen

Grundinformationen

Standard-SMILES: C#CC[Si](C)(C)C
InChIKey: ULYLMHUHFUQKOE-UHFFFAOYSA-N
Summenformel: C6H12Si
Durchschnittliche Molmasse: 112,24 g/mol
Monoisotopische Masse: 112,07082691

Namen und Bezeichner

Bevorzugter Name: Trimethyl-2-propynylsilane
IUPAC: trimethyl(prop-2-ynyl)silane
Lokaler Name: Trimethyl-2-propinylsilan
Englischer Name: PROPARGYLTRIMETHYLSILANE
Summenformel: C6H12Si
Molmasse: 112.25

Namen und Synonyme

Trimethyl-2-propynylsilaneSilane, trimethyl-2-propyn-1-yl-RefChem:89979213361-64-3PROPARGYLTRIMETHYLSILANESilane, trimethyl-2-propynyl-trimethyl(prop-2-ynyl)silanetrimethyl(prop-2-yn-1-yl)silaneSilane,trimethyl-2-propyn-1-yl-Propargyltrimethylsilane, tech gradeMFCD00042922L8BVJ8DGN6

Weitere Namen anzeigen

3-(TRIMETHYLSILYL)PROPYNE2-PROPYNYL-TRIMETHYLSILANE3-TRIMETHYLSILYL-1-PROPYNEtrimethyl-2-propynyl-silanPropargyltrimethylsilanestab1-(Trimethylsilyl)-2-propyne

C6H12SiTrimethyl(propargyl)silaneTrimethyl(2-propynyl)silane2-Propynyltrimethylsilane3-(trimethylsilyl)-1-propyneEINECS 236-427-6trimethylpropargylsilanepropargyl trimethylsilane

Datenbank-Bezeichner

CAS: 13361-64-3
PubChem CID: 83378
DTXSID: DTXSID6065426
UNII: L8BVJ8DGN6
EC Number: 236-427-6
Nikkaji: J213.873E

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 1
Schwere Atome: 7
Formalladung: 0
Komplexität: 88,5

Physikochemische Eigenschaften

Schmelzpunkt: 148 · 148-151 °C(Solv: ethyl ether (60-29-7))
Siedepunkt: 91 · 91-93 °C (lit.)
Dichte: 0.753 g/mL · 0.753 g/mL at 25 °C (lit.)
Brechungsindex: 20 · n20/D 1.413(lit.)
Flammpunkt: 13 °F · 13 °F
storage temp.: -20 °C · -20°C
Löslichkeit: 2 Cl2 · sol ether, THF, CH2Cl2.
Aggregatzustand: Liquid
Farbe: Clear yellow
BRN: 2036316 · 2036316
InChI: InChI=1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3
InChIKey: ULYLMHUHFUQKOE-UHFFFAOYSA-N
SMILES: [Si](C)(C)(C)CC#C
CAS Datenbank: 13361 · 13361-64-3
EPA chemische Informationen: -2 · Silane, trimethyl-2-propynyl- (13361-64-3)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

Sicherheitsdaten

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 2
hs_code: 29310099
risk_code: 11-36/37/38
hazard_code: F,Xi
safety_code: 16-26-36
hazard_class: 3.1
packing_group: II
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationSilane, trimethyl-2-propyn-1-yl-: INACTIVE

Anwendungen · 1 Eintrag

Verwenden3-Trimethylsilyl-1-propyne is used as propargylation agent; allenylation agent; can give addition reactions on the triple bond. It takes part in the following reactions: Propargylation Reactions, Alkylation Reactions, Reactions with Epoxides,Reactions with Aldehydes and Ketones, Reactions with Chloroformates, Reactions with Polyoxymethylene and Amines, Allenylation Reactions, Substitution Reactions, Reactions with Acetals and Hemiacetals, Reactions with Aldehydes and Ketones, Reactions with in situ Generated Iminium and α-Acyl Iminium Ions, Reactions with Acid Chlorides, Reactions with Conjugated Heteroatomic Systems, Reactions of the Triple Bond etc.