Grundinformationen
- Standard-SMILES
O=[N+]([O-])c1ccccc1Nc1ccccc1- InChIKey
RUKISNQKOIKZGT-UHFFFAOYSA-N- Summenformel
- C12H10N2O2
- Durchschnittliche Molmasse
- 214,22 g/mol
- Monoisotopische Masse
- 214,07422756
Überblick
2-nitrodiphenylamine appears as red-brown crystalline powder or reddish-brown solid. (NTP, 1992)
Namen und Bezeichner
- Bevorzugter Name
- 2-Nitrodiphenylamine
- IUPAC
- 2-nitro-N-phenylaniline
- Lokaler Name
- 2-Nitro-N-phenylanilin
- Englischer Name
- 2-Nitrodiphenylamine
- Summenformel
- C12H10N2O2
- Molmasse
- 214.22
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
119-75-5- PubChem CID
- 8407
- DTXSID
DTXSID4025749- ChEMBL
CHEMBL1450018- UNII
- DT9NA7ZDD8
- EC Number
- 204-348-6
- Nikkaji
- J37.804F
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 3,7
- Polarare Oberfläche (TPSA)
- 57,9 Ų
- H-Brücken-Donoren
- 1
- H-Brücken-Akzeptoren
- 3
- Frei drehbare Bindungen
- 2
- Schwere Atome
- 16
- Formalladung
- 0
- Komplexität
- 234
Experimentelle und physikochemische Eigenschaften
Solubility
less than 1 mg/mL at 72 °F (NTP, 1992)
1.1 [ug/mL] (The mean of the results at pH 7.4)
Melting Point
167.9 °F (NTP, 1992)
75.5 °C
Physical Description
2-nitrodiphenylamine appears as red-brown crystalline powder or reddish-brown solid. (NTP, 1992)
CBI; Liquid
Orange solid; [Reference #1] Reddish-brown solid; [CAMEO] Red or orange crystalline solid; [Alfa Aesar MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 74 · 74-76 °C(lit.)
- Siedepunkt
- 346 °C · 346 °C
- Dichte
- 1.36 · 1.36
- Dampfdichte
- 10.7 · 10.7 (vs air)
- Brechungsindex
- 1.666 · 1.6660 (estimate)
- Flammpunkt
- 346 °C · 346°C
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Löslichkeit
- Chloroform (Slightly), , DMSO (Slightly), Methanol (Slightly, Sonicated)
- Aggregatzustand
- Solid
- pka
- -3.39 · -3.39±0.20(Predicted)
- Farbe
- Red
- Wasserlöslichkeit
- negligible
- BRN
- 2213591 · 2213591
- InChIKey
- RUKISNQKOIKZGT-UHFFFAOYSA-N
- CAS Datenbank
- 119 · 119-75-5(CAS DataBase Reference)
- NIST chemische Informationen
- 2 · Benzenamine, 2-nitro-N-phenyl-(119-75-5)
- EPA chemische Informationen
- 2 · 2-Nitrodiphenylamine (119-75-5)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 60 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Chemical: Benzenamine, 2-nitro-N-phenyl-
Benzenamine, 2-nitro-N-phenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-nitro-N-phenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Benzenamine, 2-nitro-N-phenyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Sicherheit und Schutzausrüstung
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Protective Action Criteria (PAC)
12 [mg/m3]
130 [mg/m3]
790 [mg/m3]
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Toxikologische Informationen
EPA Provisional Peer-Reviewed Toxicity Values
2-Nitrodiphenylamine
PDF Document
2011
Sicherheitsdaten
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 29214400
- risk_code
- 36/37/38
- hazard_code
- Xi
- hazard_note
- Irritant
- safety_code
- 26-36-37/39
Chemie und Industrie
Verwendung und Herstellung
Uses
Used to control the combustion of propylene glycol dinitrate in Otto fuel II (US navy propellant for torpedoes and other weapons systems); Also used as a solvent dye; [ATSDR Public Health Statements] Used as stabilizer for nitroglycerin and as a chemical intermediate; [NTP]
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Benzenamine, 2-nitro-N-phenyl-: ACTIVE
Anwendungen
Verwenden(2-Nitrophenyl)phenylamine (cas# 119-75-5) is a compound useful in organic synthesis.
Verwenden2-Nitrodiphenylamine is used to control the combustion of propylene glycol dinitrate in Otto fuel II (US navy propellant for torpedoes and other weapons systems); Also used as a solvent dye; Used as stabilizer for nitroglycerin and as a chemical intermediate
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