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Oxydiethylendibenzoat

Di-O-benzoyldiethylene glycol

HCID 8437
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GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
120-55-8
Standard-SMILES
O=C(OCCOCCOC(=O)c1ccccc1)c1ccccc1
InChIKey
NXQMCAOPTPLPRL-UHFFFAOYSA-N
Summenformel
C18H18O5
Durchschnittliche Molmasse
314,3 g/mol
Monoisotopische Masse
314,11542367

Überblick

a plasticizer

Namen und Bezeichner

Bevorzugter Name
Di-O-benzoyldiethylene glycol
IUPAC
2-(2-benzoyloxyethoxy)ethyl benzoate
Lokaler Name
Oxydiethylendibenzoat
Englischer Name
Diethylene glycol dibenzoate
Summenformel
C18H18O5
Molmasse
314.33

Namen und Synonyme

Diethylene glycol dibenzoate120-55-8Benzo Flex 2-45Dibenzoyldiethyleneglycol esterDIETHYLENE GLYCOL, DIBENZOATEYAI66YDY1CBenzoflex 2-45Benzoyloxyethoxyethyl benzoateEthanol, 2,2'-oxybis-, dibenzoateBenzoic acid, diester with diethylene glycolDTXSID0026967FLEXOL 2GB
Weitere Namen anzeigen
DEGDBDEDBOxydi-2,1-ethanediyl dibenzoate2-[2-(Benzoyloxy)ethoxy]ethyl benzoatebenzoflex2-45DEG dibenzoateoxydiethylenedibenzoatediethylenebenzylbenzoate
MONOCIZER PB 3VELSICOL 2-45DTXCID006967204-407-6Di-O-Benzoyldiethylene GlycolRefChem:587361Oxybis(ethane-2,1-diyl) dibenzoateDiglycol dibenzoate

Datenbank-Bezeichner

CAS
120-55-8
PubChem CID
8437

Eigenschaften

Berechnete Struktureigenschaften

XLogP
3,4
Polarare Oberfläche (TPSA)
61,8 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
5
Frei drehbare Bindungen
10
Schwere Atome
23
Formalladung
0
Komplexität
322

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Ethylene Glycols
Polymers · 2 Einträge

Plastics -> Plasticisers

Plastics -> PVC (soft)

CosmeticsPlasticiser; Emollient
SpringerMaterials PropertiesBoiling point
Plasticizers · 2 Einträge

Plasticizer

Plasticizer

Density · 2 Einträge

1.2 @ 68 °F (20 °C)

Relative density (water = 1): 1.2

Viscosity110 mPa.s @ 20 °C
Color/FormLIQUID
Solubility · 2 Einträge

SOL IN WATER

Solubility in water: miscible

Flash Point · 2 Einträge

450 °F (232 °C) (CLOSED CUP)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

This chemical does not meet GHS hazard criteria for 78.4% (297 of 379) of all reports.

H411 (21.1%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P273, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 379 reports by companies from 6 notifications to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Ethanol, 2,2'-oxybis-, dibenzoate

Ethanol, 2,2'-oxybis-, 1,1'-dibenzoate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethanol, 2,2'-oxybis-, 1,1'-dibenzoate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Oxydiethylene dibenzoate (EC: 204-407-6)

Ethanol, 2,2'-oxybis-, dibenzoate: Non hazardous

Other Safety InformationIMAP assessments - Ethanol, 2,2'-oxybis-, dibenzoate: Human health tier I assessment
Fire HazardsCombustible.
Hazards SummaryIn oral lethal dose studies of rats, causes convulsions and other changes to the liver; [RTECS] A mild skin and eye irritant; [ICSC] See GLYCOL ETHERS.
Chemical DangersOn combustion, forms irritating fumes.
Physical DangersThe vapour is heavier than air.
NFPA Hazard Classification

Chemie und Industrie

Verwendung und Herstellung

Uses · 6 Einträge

Used as plasticizer for resins (cellulose acetate butyrate, polyvinyl acetate, cellulose nitrate, ethyl cellulose, and polymethyl methacrylate) and a stabilizer for perfumes; [HSDB]

PLASTICIZER

PLASTICIZER FOR CELLULOSE ACETATE BUTYRATE RESINS

PLASTICIZER FOR CELLULOSE NITRATE RESINS

PLASTICIZER FOR ETHYL CELLULOSE RESINS

For more Uses (Complete) data for DIETHYLENE GLYCOL, DIBENZOATE (6 total), please visit the HSDB record page.

U.S. Exports · 2 Einträge

(1979) No Data

(1981) No Data

U.S. Imports · 2 Einträge

(1979) No Data

(1981) No Data

U.S. Production · 3 Einträge

2023: 55,000,000 - <70,000,000 lb

(1979) PROBABLY GREATER THAN 2.27X10+6 GRAMS

(1981) PROBABLY GREATER THAN 2.27X10+6 GRAMS

Consumer UsesPlasticizer
Industry UsesPlasticizer
Methods of ManufacturingREACTION OF DIETHYLENE GLYCOL WITH BENZOIC ACID
Household ProductsInformation on 15 consumer products that contain 2,2-Oxybis-ethanol dibenzoate in the following categories is provided:
Use Classification · 3 Einträge

Cosmetics -> Plasticiser; Emollient

Plastics -> Polymer Type -> PVC (soft)

Plastics -> Plasticisers

General Manufacturing Information · 3 Einträge

Plastics Product Manufacturing

Ethanol, 2,2'-oxybis-, 1,1'-dibenzoate: ACTIVE

AS A STABILIZER FOR PERFUMES.

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
DTXSID
DTXSID0026967
ChEMBL
CHEMBL2130591
UNII
YAI66YDY1C
EC Number
204-407-6
Nikkaji
J46.849E

232 °C

Boiling Point · 2 Einträge

225-227 °C @ 3 MM HG

at 0.7kPa: 236 °C

Melting Point · 2 Einträge

-28 °C

28 °C

Physikochemische Eigenschaften

Schmelzpunkt
24 °C · 24°C
Siedepunkt
235 · 235-237 °C7 mm Hg(lit.)
Dichte
1.175 g/mL · 1.175 g/mL at 25 °C(lit.)
Dampfdruck
0 Pa · 0Pa at 25℃
Brechungsindex
20 · n20/D 1.544(lit.)
Flammpunkt
230 °F · >230 °F
storage temp.
Sealed in dry,Room Temperature
Löslichkeit
Chloroform (Sparingly), Methanol (Slightly)
Aggregatzustand
Oil
Farbe
Clear Colourless
Wasserlöslichkeit
38.3 mg/L · 38.3mg/L at 20℃
Henry's Law Constant
3.3 · 3.3×106 mol/(m3Pa) at 25℃, HSDB (2015)
Kosmetik-Inhaltsstoffe Funktionen
PLASTICISERSKIN CONDITIONING - EMOLLIENTHAIR CONDITIONING
InChI
1S/C18H18O5/c19-17(15-7-3-1-4-8-15)22-13-11-21-12-14-23-18(20)16-9-5-2-6-10-16/h1-10H,11-14H2
InChIKey
NXQMCAOPTPLPRL-UHFFFAOYSA-N
SMILES
O=C(OCCOCCOC(=O)c1ccccc1)c2ccccc2
LogP
3.2 at · 3.2 at 30℃
CAS Datenbank
120 · 120-55-8(CAS DataBase Reference)
NIST chemische Informationen
2 · Ethanol, 2,2'-oxybis-, dibenzoate(120-55-8)
EPA chemische Informationen
Diethylene glycol dibenzoate (120-55-8)
· 3 Einträge

0 - Materials that, under emergency conditions, would offer no hazard beyond that of ordinary combustible materials.

1 - Materials that must be preheated before ignition can occur. Materials require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur.

0 - Materials that in themselves are normally stable, even under fire conditions.

Peroxide Forming Chemical · 3 Einträge

Diethylene glycol dibenzoate

D: Other compounds that may form peroxides

Kelly

Hazard Classes and CategoriesAquatic Chronic 2 (21.1%)

Sicherheit und Schutzausrüstung

Fire FightingUse water spray, alcohol-resistant foam, powder, carbon dioxide.
First Aid Measures · 3 Einträge

Fresh air, rest.

Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Safe StorageVentilation along the floor.
Fire Fighting Procedures"ALCOHOL" FOAM. WATER OR FOAM MAY CAUSE FROTHING.
Disposal Methods · 1 Eintrag

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Spillage DisposalSweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.
Eye PreventionWear safety spectacles.
Fire PreventionNO open flames.
Inhalation RiskEvaporation at 20 °C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.
Skin PreventionProtective gloves.
Exposure PreventionPREVENT DISPERSION OF DUST!
Effects of Short Term ExposureThe substance is mildly irritating to the eyes and skin.

Toxikologische Informationen

Environmental Fate · 3 Einträge

TERRESTRIAL FATE: Based on a recommended classification scheme(1), an estimated Koc value of 540(SRC), determined from a structure estimation method(2), indicates that diethylene glycol dibenzoate will have low mobility in soil(SRC). Volatilization of diethylene glycol dibenzoate should not be important from moist soil surfaces(SRC) given an estimated Henry's Law constant of 3X10-12 atm-cu m/mole(SRC), using a recommended regression equation(3). Volatilization from dry soil surfaces(SRC) is not expected based on an estimated vapor pressure of 0.09 mm Hg(SRC), determined from a fragment constant method(4). No data are available to determine the rate or importance of biodegradation of diethylene glycol dibenzoate in soil(SRC).

AQUATIC FATE: Based on a recommended classification scheme(1), an estimated Koc value of 540(SRC), determined from a structure estimation method(2), indicates that diethylene glycol dibenzoate should adsorb to suspended solids and sediment in the water(SRC). Diethylene glycol dibenzoate will be essentially non-volatile from water surfaces(1,SRC) based on an estimated Henry's Law constant of 3X10-12 atm-cu m/mole(SRC), developed using a fragment constant estimation method(3). According to a classification scheme(5), an estimated BCF value of 120(1,SRC), from an estimated log Kow(4,SRC), suggests that bioconcentration in aquatic organisms is high(SRC). Diethylene glycol dibenzoate has an estimated base-catalyzed hydrolysis rate of 0.16 L/mol-sec at a pH of 8, which corresponds to a half-life of 49 days at a pH of 8 and 1.3 years at a pH of 7(6,SRC). Insufficient data are available to determine the rate or importance of biodegradation of diethylene glycol dibenzoate in water(SRC).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), diethylene glycol dibenzoate, which has an estimated vapor pressure of 0.09 mm Hg at 25 °C(2,SRC), will exist solely as a vapor in the ambient atmosphere. Vapor-phase diethylene glycol dibenzoate is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be about 20 hours(3,SRC). Particulate-phase diethylene glycol dibenzoate may be physically removed from the air by wet and dry deposition(SRC).

Adverse EffectsNeurotoxin - Other CNS neurotoxin
Exposure RoutesThe substance can be absorbed into the body by inhalation.
Signs and Symptoms · 2 Einträge

Redness.

Redness.

Soil Adsorption/Mobility · 1 Eintrag

Using a structure estimation method based on molecular connectivity indices(1), the Koc for diethylene glycol dibenzoate can be estimated to be about 540(SRC). According to a recommended classification scheme(2), this estimated Koc value suggests that diethylene glycol dibenzoate has low mobility in soil(SRC).

Artificial Pollution SourcesDiethylene glycol dibenzoate's production and use as an plasticizer(1) may result in its release to the environment through various waste streams(SRC).
Environmental Bioconcentration · 1 Eintrag

An estimated BCF value of 120 was calculated for diethylene glycol dibenzoate(SRC), using an estimated log Kow of 3.04(1,SRC) and a recommended regression-derived equation(2). According to a classification scheme(3), this BCF value suggests that bioconcentration in aquatic organisms is high(SRC).

Volatilization from Water/Soil · 1 Eintrag

The Henry's Law constant for diethylene glycol dibenzoate is estimated as 3X10-12 atm-cu m/mole(SRC) using a fragment constant estimation method(1). This value indicates that diethylene glycol dibenzoate will be essentially nonvolatile from water surfaces(2,SRC). Diethylene glycol dibenzoate's estimated values for vapor pressure, 0.09 mm Hg(3,SRC) and Henry's Law constant(1,SRC) indicate that volatilization from dry and moist soil surfaces should not occur(SRC).

Environmental Abiotic Degradation · 1 Eintrag

The rate constant for the vapor-phase reaction of diethylene glycol dibenzoate with photochemically produced hydroxyl radicals has been estimated as 1.8X10-11 cu cm/molecule-sec at 25 °C(SRC) using a structure estimation method(1,SRC). This corresponds to an atmospheric half-life of about 20 hours at an atmospheric concentration of 5X10+5 hydroxyl radicals per cu cm(1,SRC). Diethylene glycol dibenzoate has an estimated base-catalyzed hydrolysis rate of 0.16 L/mol-sec at a pH of 8, which corresponds to a half-life of 49 days at a pH of 8 and 1.3 years at a pH of 7(2,SRC).

Probable Routes of Human Exposure · 1 Eintrag

NIOSH (NOES Survey 1981-1983) has statistically estimated that 25,414 workers (10,937 of these are female) are potentially exposed to diethylene glycol dibenzoate in the USA(1). Occupational exposure may be through inhalation and dermal contact with this compound(SRC).

Environmental Fate/Exposure Summary · 1 Eintrag

Diethylene glycol dibenzoate's production and use as a plasticizer may result in its release to the environment through various waste streams. If released to soil, diethylene glycol dibenzoate will have low mobility based on an estimated Koc value of 540. Volatilization of diethylene glycol dibenzoate is not expected to be important from moist soil surfaces given an estimated Henry's Law constant of 3X10-12 atm-cu m/mole. Volatilization from dry soil surfaces is not expected based on an estimated vapor pressure of 0.09 mm Hg. Insufficient data are available to determine the rate or importance of biodegradation of diethylene glycol dibenzoate in soil or water. If released to water, diethylene glycol dibenzoate is expected to adsorb to suspended solids and sediment based on an estimated Koc value of 540. Diethylene glycol dibenzoate will be essentially non-volatile from water surfaces based on an estimated Henry's Law constant of 3X10-12 atm-cu m/mole. An estimated BCF value of 120 suggests that bioconcentration in aquatic organisms is high. Diethylene glycol dibenzoate has estimated base-catalyzed hydrolysis half-lives of 49 days at a pH of 8 and 1.3 years at a pH of 7. If released to the atmosphere, diethylene glycol dibenzoate, which has an estimated vapor pressure of 0.09 mm Hg, will exist solely as a vapor. Vapor-phase diethylene glycol dibenzoate is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals with an estimated half-life of about 20 hours. Particulate-phase diethylene glycol dibenzoate may be physically removed from the air by wet and dry deposition. Occupational exposure may be through inhalation and dermal contact with this compound. (SRC)

Sicherheitsdaten

wgk
2
tsca
TSCA listed
hs_code
29163100
RTECS-Nr.
ID6650000
safety_code
24/25
Speicherklasse
10 - Combustible liquids
Giftige Stoffe Daten
120-55-8(Hazardous Substances Data)

Anwendungen

VerwendenDiethylene Glycol Dibenzoate is used in analytical studies to investigation into the migration potential of coating materials from cookware products.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Diethylenglykol

Anbieter100 Anbieter

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