HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
1-Nitroso-2-naphthol
CI NO 10005 · Cobalt reagent · zelenmoridlova4 · Compound Fr12178 · Zelen moridlova 4 · 1-Nitroso-2-phthol · Nitroso-2-Naphthol · Nitroso-β-naphthol
Identifikatoren & physikalische Daten
| CAS No. | 131-91-9 |
|---|---|
| Summenformel | C10H7NO2 |
| Durchschnittliche Molmasse | 173,17 g/mol |
| Monoisotopische Masse | 173,04767847 g/mol |
| SMILES | O=Nc1c(O)ccc2ccccc12 |
| InChIKey | YXAOOTNFFAQIPZ-UHFFFAOYSA-N |
| PubChem CID | 8580 |
| ChEBI | CHEBI:194993 |
| EC No. | 205-043-0 |
| DTXSID | DTXSID9059622 |
| Lokaler Name | 1-Nitroso-2-naphthol |
Chemische & physikalische Eigenschaften
| XLogP | 2,3 |
|---|---|
| Polarare Oberfläche (TPSA) | 49,7 |
| H-Brücken-Donoren | 1 |
| H-Brücken-Akzeptoren | 3 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 13 |
| Formalladung | 0 |
| Komplexität | 195 |
| Dampfdruck | 0.0000911 [mmHg] |
| Physical Description | Yellowish-brown solid[Merck Index] Brown powder[Alfa Aesar MSDS] |
| Schmelzpunkt | 106-108 °C (dec.) (lit.) |
| Siedepunkt | 303.81°C (rough estimate) |
| Dichte | 1.2427 (rough estimate) |
| Brechungsindex | 1.5200 (estimate) |
| Lagerbedingungen | Keep in dark place,Sealed in dry,Room Temperature |
| pKa (Säurekonstante) | 7.87±0.10(Predicted) |
| Aggregatzustand | crystalline |
| Farbe | tan to brown |
| Löslichkeit | insoluble |
| Merck | 14,6641 |
| BRN | 776947 |
| InChI | 1S/C10H7NO2/c12-9-6-5-7-3-1-2-4-8(7)10(9)11-13/h1-6,12H |
| InChIKey | YXAOOTNFFAQIPZ-UHFFFAOYSA-N |
| SMILES | Oc1ccc2ccccc2c1N=O |
| CAS Datenbank | 131-91-9(CAS DataBase Reference) |
| NIST chemische Informationen | 2-Naphthalenol, 1-nitroso-(131-91-9) |
| EPA chemische Informationen | 2-Naphthalenol, 1-nitroso- (131-91-9) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]H315 (95.7%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (95.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (93.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]H400 (12.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 47 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Regulatorische Informationen | Chemical: 2-Naphthalenol, 1-nitroso-2-Naphthalenol, 1-nitroso-: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | A skin and strong eye irritantHarmful by ingestion[Alfa Aesar MSDS] See 2-Nitroso-1-naphthol. |
| Hazard Classes and Categories | Acute Tox. 4 (95.7%)Skin Irrit. 2 (95.7%)Eye Irrit. 2A (95.7%)STOT SE 3 (93.6%)Aquatic Acute 1 (12.8%) |
| F | 8 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN3077 |
| Zollcode | 29089000 |
| RTECS-Nr. | QL4725000 |
| R-Sätze (R) | 22-36/37/38-33-20/21/22 |
| Toxizität | LDLo orl-rat: 500 mg/kg NCNSA6 5,35,53 |
| Gefahrensymbole | Xn |
| Sicherheitshinweise (S) | 26-36-45 |
| Gefahrenklasse | 9Acute Tox. 4 OralEye Irrit. 2Muta. 2Skin Irrit. 2Skin Sens. 1 |
| Verpackungsgruppe | III |
| Lagerklasse | 11 - Combustible Solids |
Anwendungen & Verwendung
Verwenden
1-Nitroso-2-naphthol as a complexing agent for the on-line preconcentration of cobalt with FI-FAAS. 1-Nitroso-2-naphthol is the chelating ion-exchanger in the synthesis of alumina adsorbents that are of acidic, basic and neutral nature. It is used for the removal and preconcentration of Pb(II), Cu(II), Cr(III) from waste, as well as drinking water. It is also used in the preconcentration of cobalt using C(18) microcolumn with flow injection that is coupled to a flame atomic absorption spectrometry (FI-FAAS) system. 1-Nitroso-2-naphthol is used in the preparation of 1-nitroso-2-naphthol-sodium nitrite reagent.