Peroxydikohlensäure-bis(2-ethylhexyl)ester
Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester
Grundinformationen
- CAS
16111-62-9- Standard-SMILES
CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC- InChIKey
ZACVGCNKGYYQHA-UHFFFAOYSA-N- Summenformel
- C18H34O6
- Durchschnittliche Molmasse
- 346,5 g/mol
- Monoisotopische Masse
- 346,23553881
Überblick
This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.
Namen und Bezeichner
- Bevorzugter Name
- Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester
- IUPAC
- 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate
- Lokaler Name
- Peroxydikohlensäure-bis(2-ethylhexyl)ester
- Englischer Name
- Di-(2-ethylhexyl)peroxydicarbonate
- Summenformel
- C18H34O6
- Molmasse
- 346.46
Namen und Synonyme
16111-62-9Peroxydicarbonic acid, bis(2-ethylhexyl) esterDi(2-ethylhexyl) peroxydicarbonateBis(2-ethylhexyl) peroxydicarbonateEINECS 240-282-4BRN 5964960di-(2-Ethylhexyl)peroxydicarbonateDTXSID5027778Peroxydicarbonic acid, di(2-ethylhexyl) esterEC 240-282-4Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) esterDI-(2-ETHYLHEXYL) PEROXYDICARBONATE, (TECHNICALLY PURE)
Weitere Namen anzeigen
Lupersol 223Trigonox EHP-C75Trigonox EHP-W60Trigonox EHPS-C75Initiating agent EHPDEHP peroxydicarbonate2-Ethylhexyl percarbonateBis(2-ethylhexyl) perdicarbonate
DI-(2-ETHYLHEXYL) PEROXYDICARBONATE, [TECHNICALLY PURE]RefChem:860365ESPERCARB 840MTRIGONOX EHP-W 40DTXCID407778di-2-ethylhexyl peroxydicarbonate240-282-42-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate
Datenbank-Bezeichner
- CAS
16111-62-9- PubChem CID
- 85963
- DTXSID
DTXSID5027778- EC Number
- 240-282-4
- Nikkaji
- J9.287H
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 7,3
- Polarare Oberfläche (TPSA)
- 71,1 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 6
- Frei drehbare Bindungen
- 17
- Schwere Atome
- 24
- Formalladung
- 0
- Komplexität
- 299
Experimentelle und physikochemische Eigenschaften
Physical Description
This liquid peroxide is particularly sensitive to temperature rises. Above a given "Control Temperature" they decompose violently. They are generally stored or transported in a solvent slurry.
Liquid; CBI
Physikochemische Eigenschaften
- Siedepunkt
- 401.18 °C · 401.18°C (rough estimate)
- Dichte
- 1.0722 · 1.0722 (rough estimate)
- Dampfdruck
- 0.001 Pa · 0.001Pa at 25℃
- Brechungsindex
- 1.445 · 1.4450 (estimate)
- Wasserlöslichkeit
- 880 mg/L · 880mg/L at 25℃
- Stabilität
- Unstable if heated. Heating presents a potential risk of explosion. May be shock sensitive. Flammable. May react violently with organic materials.
- LogP
- 2.73 · 2.73
- EPA chemische Informationen
- Peroxydicarbonic acid, bis(2-ethylhexyl) ester (16111-62-9)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Danger
H242 (100%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]
P210, P234, P235, P240, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403, P410, P411, P420, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 559 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Chemical: Peroxydicarbonic acid, bis(2-ethylhexyl) ester
Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 31-05-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/14207
Peroxydicarbonic acid, bis(2-ethylhexyl) ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
DOT LabelOrganic Peroxide
Fire HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Health HazardsExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity Profile
DI-(2-ETHYLHEXYL) PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10 °C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156], Danger of explosion when dry
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and CategoriesOrg. Perox. C (100%)
Sicherheit und Schutzausrüstung
Fire FightingExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
First AidExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Nonfire Spill ResponseExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Sicherheitsdaten
- tsca
- TSCA listed
- ridadr
- 3117
- hazard_class
- 5.2
- packing_group
- II
Chemie und Industrie
Verwendung und Herstellung
U.S. Production2023: 4,000,000 - <5,500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesPolymerization promoter
General Manufacturing Information
Plastics Material and Resin Manufacturing
Peroxydicarbonic acid, C,C'-bis(2-ethylhexyl) ester: ACTIVE
Vor- und nachgelagerte Produkte
Vorgelagerte Rohstoffe
Zugehörige Reaktionen
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