Carbonylhydrotris(triphenylphosphin)iridium
Carbonylhydrotris(triphenylphosphine)iridium
Grundinformationen
- CAS
17250-25-8- Standard-SMILES
[C-]#[O+].[H-].[Ir].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1- InChIKey
OWVGPTPQWABNND-UHFFFAOYSA-N- Summenformel
- C55H46IrOP3-
- Durchschnittliche Molmasse
- 1.008,1 g/mol
- Monoisotopische Masse
- 1.008,23908
Namen und Bezeichner
- Bevorzugter Name
- Carbonylhydrotris(triphenylphosphine)iridium
- IUPAC
- carbon monoxide;hydride;iridium;tris(triphenylphosphane)
- Lokaler Name
- Carbonylhydrotris(triphenylphosphin)iridium
- Englischer Name
- HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
- Summenformel
- C55H45IrOP3
- Molmasse
- 1007.08
Namen und Synonyme
Carbonylhydrotris(triphenylphosphine)iridiumEINECS 241-282-7Iridium, carbonylhydrotris(triphenylphosphine)-Carbonyltris(triphenylphosphine)hydridoiridium(I)RefChem:574583DTXSID10889388DTXCID701782074241-282-717250-25-8CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)Ir18.6%minDichlorodicarbonyl ruthenium
Weitere Namen anzeigen
carbonylhydrotris(triphenylphosphine)-iridiuHydrocarbonyltris(triphenylphosphine)iridiumHydridocarbonyltris-(triphenylphosphino)-iridiumhydridocarbonyltris (triphenylphosphine) iridiuM
Datenbank-Bezeichner
- CAS
17250-25-8- PubChem CID
- 87018
- EC Number
- 241-282-7
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 1 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 9
- Schwere Atome
- 60
- Formalladung
- -1
- Komplexität
- 214
Physikochemische Eigenschaften
- Schmelzpunkt
- 170 °C · 170°C (dec.)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- Löslichkeit
- Soluble in chloroform and toluene
- Aggregatzustand
- Powder
- Farbe
- light yellow
- CAS Datenbank
- 17250 · 17250-25-8
- EPA chemische Informationen
- Iridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Danger
H301+H311+H331 (20%): Toxic if swallowed, in contact with skin or if inhaled [Danger Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]
P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P319, P321, P330, P332+P317, P337+P317, P361+P364, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 5 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Hazard Classes and CategoriesAcute Tox. 3 (20%)
Sicherheitsdaten
- tsca
- TSCA listed
- ridadr
- UN2813
- hs_code
- 2843.90.0000
- risk_code
- 36/37/38
- hazard_code
- Xn
- safety_code
- 26-36/37/39
- hazard_class
- 4.3
- packing_group
- III
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing InformationIridium, carbonylhydrotris(triphenylphosphine)-: INACTIVE
Anwendungen
VerwendenHydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
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