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Dibutylsuccinat

Dibutyl succinate

HCID 8830
NotizenReaktionen
GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
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Grundinformationen

CAS
141-03-7
Standard-SMILES
CCCCOC(=O)CCC(=O)OCCCC
InChIKey
YUXIBTJKHLUKBD-UHFFFAOYSA-N
Summenformel
C12H22O4
Durchschnittliche Molmasse
230,3 g/mol
Monoisotopische Masse
230,15180918

Überblick

Dibutyl succinate is a member of dicarboxylic acids and O-substituted derivatives and a diester.

Namen und Bezeichner

Bevorzugter Name
Dibutyl succinate
IUPAC
dibutyl butanedioate
Lokaler Name
Dibutylsuccinat
Englischer Name
Dibutyl succinate
Summenformel
C12H22O4
Molmasse
230.3

Namen und Synonyme

DIBUTYL SUCCINATE141-03-7Dibutyl butanedioateTabutrexDibutylsuccinateSuccinic acid di-n-butyl esterDi-n-butyl succinateTabatrexButanedioic acid, dibutyl esterButyl butanedioateSuccinic acid dibutyl ester1,4-dibutyl butanedioate
Weitere Namen anzeigen
Butyl succinateent666TabetrexTABATREX(R)
DNBSSuccinic acid, dibutyl esterButanedioic acid dibutyl esterButanedioic acid, 1,4-dibutyl esterENT 666NSC 1502MFCD00040495DTXSID7021998

Datenbank-Bezeichner

CAS
141-03-7
PubChem CID
8830
DTXSID
DTXSID7021998
ChEMBL
CHEMBL1788388
ChEBI
CHEBI:82263
UNII
Q050512U41
EC Number
205-449-8
Nikkaji
J5.801G

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,9
Polarare Oberfläche (TPSA)
52,6 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
11
Schwere Atome
16
Formalladung
0
Komplexität
179

Experimentelle und physikochemische Eigenschaften

SpringerMaterials PropertiesBoiling point
PesticidesPesticides -> Insect Repellents
Density0.9768 @ 20 °C/4 °C
Flavoring AgentsEU Flavoring substances
Color/FormColorless liquid
Solubility · 3 Einträge

MISCIBLE WITH MOST ORG SOLVENTS INCLUDING PETROLEUM OILS

Soluble in ethanol, ethyl ether, and benzene.

In water, 2.30X10+2 mg/l, temperature not specified.

CorrosivityNON-CORROSIVE
Flash Point275 °F (Open Cup)
Boiling Point274.5 °C
DecompositionWhen heated to decomposition it emits acrid smoke and irritating fumes.

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 3 Einträge

This chemical does not meet GHS hazard criteria for 99.5% (193 of 194) of all reports.

Not Classified

Aggregated GHS information provided per 194 reports by companies from 2 notifications to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Butanedioic acid, dibutyl ester

Commission Regulation (EC) No 1565/2000 (Repealed by Com. Implementing Reg. (EU) No 872/2012)

Butanedioic acid, dibutyl ester: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to human health
Hazards Summary · 1 Eintrag

No unreasonable adverse effects, but organic-vapor respirator recommended during mixing, loading, and application because of concern about chemical pneumonia for handlers; Only the methyl esters of fatty acids were assessed. The other 5 products are not registered and are not being supported for reregistration; [Reference #1] May cause irritation; [MSDSonline]

EPA Safer ChemicalChemical: Dibutyl succinate
FIFRA Requirements · 1 Eintrag

As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their future use. Under this pesticide reregistration program, EPA examines health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether they are eligible for reregistration. In addition, all pesticides must meet the new safety standard of the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA, as amended in 1988, were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern and List D pesticides of less concern. Dibutyl succinate is found on List D. Case No: 4005; Pesticide type: insecticide, herbicide, antimicrobial; Case Status: OPP is reviewing data from the pesticide's producers regarding its human health and/or environmental effects, or OPP is determining the pesticide's eligibility for reregistration and developing the Reregistration Eligibility Decision (RED) document.; Active ingredient (AI): Dibutyl succinate; AI Status: The active ingredient is no longer contained in any registered pesticide products ... "cancelled."

Chemie und Industrie

Pharmakologische Informationen

ATC Code · 2 Einträge

P - Antiparasitic products, insecticides and repellents

QP - Antiparasitic products, insecticides and repellents

Absorption, Distribution and ExcretionNOT DETECTABLE IN THE MILK OF A COW SPRAYED DAILY FOR 3 WK @ SEVERAL TIMES THE RECOMMENDED DOSAGE.

Verwendung und Herstellung

Uses · 4 Einträge

Used as insect repellent primarily against biting flies of cattle and also against household ants and roaches; [HSDB]

Farming (Pesticides) [Category: Industry]

For Dibutyl succinate (USEPA/OPP Pesticide Code: 077802) there are 0 labels match. /SRP: Not registered for current use in the U.S., but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./

Insect repellent especially against biting flies of cattle and household ants and roaches. /Former use/

Methods of ManufacturingPrepn from butyl alcohol and succinic acid: Vogel, J Chem Soc 1948, 624.
Formulations/Preparations · 2 Einträge

USEPA/OPP Pesticide Code 077802; Trade Names: Tabutrex.

IT IS NORMALLY FORMULATED WITH OLEIC ACID TO PROLONG ACTIVITY; EMULSIFIABLE CONCENTRATE (20%); PETROLEUM DISTILLATE SPRAY (2%).

Use Classification · 2 Einträge

EPA Safer Chemical Functional Use Classes -> Solvents

Safer Chemical Classes -> Green half-circle - The chemical is expected to be of low concern

General Manufacturing Information · 4 Einträge

Butanedioic acid, 1,4-dibutyl ester: ACTIVE

... INTRODUCED ABOUT 1955 BY GLENN CHEMICAL COMPANY, AS AN INSECT REPELLENT.

IN LIVESTOCK INSECTICIDE SPRAYS OR AEROSOLS (2%), BACKRUBBER OILS (1%), OR "STICKS" (5%) AS A REPELLENT FOR FACE FLIES, BITING FLIES, & HOUSEFLIES.

Zugehörige Reaktionen

2
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 1024144
HRID 1024144als Produktuspto-grants-2014_05
Reaktionsgleichung von HRID 1960104
HRID 1960104als Produktuspto-grants-2013_04

Notizen zur Verbindung

Wird geladen…

Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Melting Point
-29.0 °C
Refractive IndexIndex of refraction: 1.4299 @ 20 °C/D

Physikochemische Eigenschaften

Schmelzpunkt
-29 ℃ · -29℃
Siedepunkt
274 °C · 274 °C
Dichte
0 · 0,98 g/cm3
Brechungsindex
20 · nD20 1.4299
Flammpunkt
144 °C · 144 °C
Farbe
Colorless to Almost colorless
Wasserlöslichkeit
229.9 mg/L · 229.9mg/L(temperature not stated)
InChI
InChI=1S/C12H22O4/c1-3-5-9-15-11(13)7-8-12(14)16-10-6-4-2/h3-10H2,1-2H3
InChIKey
YUXIBTJKHLUKBD-UHFFFAOYSA-N
SMILES
C(OCCCC)(=O)CCC(OCCCC)=O
LogP
3.386 · 3.386 (est)
CAS Datenbank
141 · 141-03-7(CAS DataBase Reference)
NIST chemische Informationen
Dibutyl succinate(141-03-7)
EPA chemische Informationen
Dibutyl succinate (141-03-7)
Hazard Classes and CategoriesNot Classified

Sicherheit und Schutzausrüstung

Disposal Methods · 1 Eintrag

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Toxikologische Informationen

Human Toxicity ExcerptsNot irritating to skin or mucous membranes.
Non-Human Toxicity Excerpts · 3 Einträge

... OF LOW ACUTE ORAL TOXICITY IN LAB ANIMALS. NOT IRRITATING TO SKIN OR MUCOUS MEMBRANES.

... RATS FED 90 DAYS ON A DIET CONTAINING 5% SUFFERED NO ILL EFFECTS.

Mildly toxic by ingestion.

Antidote and Emergency Treatment · 2 Einträge

/SRP:/ Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poison A and B/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in respiratory arrest. Positive pressure ventilation techniques with a bag valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam (Valium) ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poison A and B/

Non-Human Toxicity ValuesLD50 Rat oral 8000 mg/kg

Regulatorische Informationen

FIFRA Requirements · 1 Eintrag

As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their future use. Under this pesticide reregistration program, EPA examines health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether they are eligible for reregistration. In addition, all pesticides must meet the new safety standard of the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA, as amended in 1988, were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern and List D pesticides of less concern. Dibutyl succinate is found on List D. Case No: 4005; Pesticide type: insecticide, herbicide, antimicrobial; Case Status: OPP is reviewing data from the pesticide's producers regarding its human health and/or environmental effects, or OPP is determining the pesticide's eligibility for reregistration and developing the Reregistration Eligibility Decision (RED) document.; Active ingredient (AI): Dibutyl succinate; AI Status: The active ingredient is no longer contained in any registered pesticide products ... "cancelled."

Sicherheitsdaten

wgk
2
tsca
TSCA listed
ridadr
UN 3082
hs_code
29171900
RTECS-Nr.
WM6250000
risk_code
51/53
hazard_code
N
safety_code
61
Giftige Stoffe Daten
141-03-7(Hazardous Substances Data)

Dibutyl succinate and/or dimethyl disulfide, preferably incorporated into polymer pellets, are mosquito attractants. In trapping expt in a barn, dibutyl succinate, and to a slightly lesser degree dimethyl disulfide, attracted more mosquitos than the std Golden Marlin. Many paper examples of polymers suitable for incorporation are given. Extrusion of the attractants containing polymers is discussed.

Anwendungen

VerwendenDibutyl succinate especially against biting flies of cattle, household ants and roaches.

Vor- und nachgelagerte Produkte

Nachgelagerte Produkte

Pigment Red 122Dibutylmaleat

Anbieter100 Anbieter

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