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Bormonophosphid

Boron phosphide

HCID 88409
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TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
12008-82-1
Standard-SMILES
B#P
InChIKey
FFBGYFUYJVKRNV-UHFFFAOYSA-N
Summenformel
BP
Durchschnittliche Molmasse
41,79 g/mol
Monoisotopische Masse
41,9830672

Überblick

Boron phosphide is a phosphide of boron. It is a semiconductor. Metal phosphides are hydrolysed to phosphine upon contact with water or stomach acid. Phosphine is a colorless, flammable, explosive, and toxic gas. (L980, L983)

Namen und Bezeichner

Bevorzugter Name
Boron phosphide
IUPAC
boranylidynephosphane
Lokaler Name
Bormonophosphid
Englischer Name
BORON PHOSPHIDE
Summenformel
BP
Molmasse
41.78

Namen und Synonyme

Boron phosphide (BP)boranylidynephosphaneBoron phosphideTridecaboron diphosphide20205-91-8Boron phosphide (B13P2)EINECS 234-542-6EINECS 243-593-3DTXSID1066570RefChem:121034DTXCID9036220234-542-6
Weitere Namen anzeigen
Phosphinidyneboronboronphosphide(bp)Boron phosphide, Technical GradeBORON PHOSPHIDE ISO 9001:2015 REACH
Boron monophosphide12008-82-1SCHEMBL136950Q2982798

Datenbank-Bezeichner

CAS
12008-82-1、20205-91-8
PubChem CID
88409
DTXSID
DTXSID1066570
EC Number
234-542-6、243-593-3
Nikkaji
J96.049G

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
2
Formalladung
0
Komplexität
10

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Phosphides
SpringerMaterials Propertiesthermal expansion coefficient
Physical DescriptionGray powder; [MSDSonline]

Physikochemische Eigenschaften

Löslichkeit
2 O, · reacts with H2O, acid solutions
Aggregatzustand
red cubic crystals or powder
Farbe
Red
Wasserlöslichkeit
2 O · reacts with H2O and acids, releasing toxic fumes [HAW93]
Knoop Microhardness
37000 · 37000, N/mm2
EPA chemische Informationen
Boron phosphide (BP) (20205-91-8)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H260 (100%): In contact with water releases flammable gases which may ignite spontaneously [Danger Substances and mixtures which in contact with water, emit flammable gases]

P223, P231+P232, P264, P270, P280, P301+P316, P302+P335+P334, P321, P330, P370+P378, P402+P404, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 4 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazards SummaryToxic by ingestion; A skin, eye, and respiratory tract irritant; Contact with water liberates flammable gases (phosphine and phosphorus oxides); [MSDSonline] See PHOSPHIDES.

Toxikologische Informationen

TreatmentAs there is no antidote for phosphine poisoning, treatment is mainly symptomatic. Artificial respiration, gastric lavage, and/or administration of activated charcoal may be necessary. (L982)
Health Effects · 1 Eintrag

Inhalation of phosphine may cause severe pulmonary irritation leading to acute pulmonary oedema, cardiovascular dysfunction, CNS excitation, coma and death. Gastrointestinal disorders, renal damage and leukopenia may also occur. Chronic exposure to phosphine can result in anemia, bronchitis, gastrointestinal effects, and visual, speech and motor problems. (L980, L982)

Exposure RoutesOral (L982) ; inhalation (L982)
Toxicity Summary · 1 Eintrag

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Phosphine and metal phosphides may be absorbed following ingestion or inhalation, then distribute to the nervous system, liver, and kidney. In the body, metal phosphides are hydrolysed to phosphine, and phosphine is oxidized to hypophosphite and phosphite. Metabolites are excreted in the urine, while unchanged phosphine is exhaled. (L982)

Verwendung und Herstellung

UsesBoron phosphide is a semiconductor. (L983)
General Manufacturing Information · 2 Einträge

Boron phosphide (B13P2): INACTIVE

Boron phosphide (BP): INACTIVE

Anbieter3 Anbieter

陕西缔都医药化工有限公司+86-29-81139210 +86-17392587031 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]

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Phosphine inhibits cytochrome c oxidase, preventing mitochondrial oxidative phosphorylation. This non-competitive inhibition prevents cellular respiration and leads to multi-organ dysfunction. Phosphine can also react with hydrogen peroxide to form the highly reactive hydroxyl radical, which can cause lipid peroxidation. (A291, A292)

Signs and Symptoms · 1 Eintrag

Early symptoms of acute phosphine intoxication include pain in the diaphragm, nausea, vomiting, excitement, and a phosphorus smell on the breath. Higher levels can cause weakness, bronchitis, pulmonary edema, shortness of breath, convulsions, and death. Some effects, such as pulmonary edema, convulsions, and liver injury, may appear or continue to be present days after an exposure. Ingestion of metal phosphides results in release of phosphine in your stomach which can cause nausea, vomiting, abdominal pain, and diarrhea. (L980)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

tsca
TSCA listed