(Fluoren-9-yl)methanol

9H-Fluorene-9-methanol

HCID 90466CAS 24324-17-2

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Grundinformationen

Standard-SMILES: OCC1c2ccccc2-c2ccccc21
InChIKey: XXSCONYSQQLHTH-UHFFFAOYSA-N
Summenformel: C14H12O
Durchschnittliche Molmasse: 196,24 g/mol
Monoisotopische Masse: 196,088815

Namen und Bezeichner

Bevorzugter Name: 9H-Fluorene-9-methanol
IUPAC: 9H-fluoren-9-ylmethanol
Lokaler Name: (Fluoren-9-yl)methanol
Englischer Name: 9-Fluorenemethanol
Summenformel: C14H12O
Molmasse: 196.24

Namen und Synonyme

24324-17-29H-Fluorene-9-methanolFluorene-9-methanol(Fluoren-9-yl)methanolEINECS 246-167-5DTXSID7066980RefChem:549969DTXCID1037064246-167-59-Fluorenemethanol9-Fluorenylmethanol9H-Fluoren-9-ylmethanol

Weitere Namen anzeigen

FMOC-OHFMOLFM-OHFoMc-OHFluorenemethanolFLUORENYL METHANOLHOFMFMOC-hydroxy

(9h-fluoren-9-yl)methanol9-(Hydroxymethyl)fluorene9-HydroxymethylfluoreneMFCD000011399-Fluorenyl Methanolfluoren-9-ylmethan-1-ol9-fluorenmethanol9-FluorenYl-Methanol

Datenbank-Bezeichner

CAS: 24324-17-2
PubChem CID: 90466
DTXSID: DTXSID7066980
UNII: AWJ7E4RKJ8
EC Number: 246-167-5
Nikkaji: J208.517H

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 2,7
Polarare Oberfläche (TPSA): 20,2 Å²
H-Brücken-Donoren: 1
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 1
Schwere Atome: 15
Formalladung: 0
Komplexität: 203

Experimentelle und physikochemische Eigenschaften

LogP2.89

Endocrine DisruptorsPotential endocrine disrupting compound

Physikochemische Eigenschaften

Schmelzpunkt: 105 · 105-107 °C (lit.)
Siedepunkt: 293.14 °C · 293.14°C (rough estimate)
Dichte: 1.0304 · 1.0304 (rough estimate)
Brechungsindex: 1.5385 · 1.5385 (estimate)
storage temp.: Sealed in dry,Room Temperature
Löslichkeit: Soluble in methanol.
Aggregatzustand: Crystalline Powder
pka: 13.68 · 13.68±0.10(Predicted)
Farbe: White to pale yellow
BRN: 2330017 · 2330017
InChI: InChI=1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2
InChIKey: XXSCONYSQQLHTH-UHFFFAOYSA-N
SMILES: C1(CO)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS Datenbank: 24324 · 24324-17-2(CAS DataBase Reference)
NIST chemische Informationen: -9 · Fluorene-9-methanol(24324-17-2)
EPA chemische Informationen: 9 H-Fluorene-9-methanol · 9H-Fluorene-9-methanol (24324-17-2)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Gefahrenhinweise

Hazard Classes and CategoriesAcute Tox. 4 (100%)

Sicherheitsdaten

wgk: 3
tsca: TSCA listed
hs_code: 29062900
risk_code: 36/37/38
hazard_code: Xi
hazard_note: Irritant
safety_code: 22-24/25-36/37/39-27-26
Speicherklasse: 11 - Combustible Solids

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing Information9H-Fluorene-9-methanol: INACTIVE

Anwendungen · 1 Eintrag

Verwenden9-Fluorenylmethanol(FMOC-OH) acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film.