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2,2'-[Methylenbis(p-phenylenoxymethylen)]bisoxiran

Bisphenol F diglycidyl ether

HCID 91511
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Grundinformationen

CAS
2095-03-6
Standard-SMILES
c1cc(OCC2CO2)ccc1Cc1ccc(OCC2CO2)cc1
InChIKey
XUCHXOAWJMEFLF-UHFFFAOYSA-N
Summenformel
C19H20O4
Durchschnittliche Molmasse
312,4 g/mol
Monoisotopische Masse
312,13615911

Namen und Bezeichner

Bevorzugter Name
Bisphenol F diglycidyl ether
IUPAC
2-[[4-[[4-(oxiran-2-ylmethoxy)phenyl]methyl]phenoxy]methyl]oxirane
Lokaler Name
2,2'-[Methylenbis(p-phenylenoxymethylen)]bisoxiran
Englischer Name
BISPHENOL F DIGLYCIDYL ETHER
Summenformel
C19H20O4
Molmasse
312.36

Namen und Synonyme

Bisphenol F diglycidyl etherCHEBI:142451BFDGE cpdRefChem:917346DTXSID50883204254-641-839817-09-9Methane, bis((2,3-epoxypropoxy)phenyl)-Oxirane, 2,2'-(methylenebis(phenyleneoxymethylene))bis-2095-03-6Bis(4-glycidyloxyphenyl)methanepara-para-BFDGE
Weitere Namen anzeigen
Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-Einecs 218-257-4Bisphenol A Impurity 9Bisoprolol Impurity 62liquid bisphenol F epoxy resins
Bis[4-(glycidyloxy)phenyl]methaneBFDGEp,p-BFDGE2-[[4-[[4-(oxiran-2-ylmethoxy)phenyl]methyl]phenoxy]methyl]oxiraneBis[4-[(oxiran-2-yl)methoxy]phenyl]methaneDiphenylolmethane diglycidyl etherbis(4-(oxiran-2-ylmethoxy)phenyl)methane4,4'-Methylenebisphenol diglycidyl ether

Datenbank-Bezeichner

CAS
2095-03-6、39817-09-9
PubChem CID

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

XLogP
3,2
Polarare Oberfläche (TPSA)
43,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
8
Schwere Atome
23
Formalladung
0
Komplexität
324

Experimentelle und physikochemische Eigenschaften

Physical DescriptionMethylene bis(phenyleneoxymethylene)bisoxirane is a colorless liquid resin.
Kovats Retention Index2704
Collision Cross Section169.0 Ų [M+Na]+ [CCS Type: DT; Buffer gas: N2; Ionization: ESI+; Dataset: TOXCAST; Source Identifier: DTXSID4044872]

Physikochemische Eigenschaften

Schmelzpunkt
15 °C · −15 °C(lit.)
Siedepunkt
474 · 474.0±25.0 °C(Predicted)
Dichte
1.19 g/mL · 1.19 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.579(lit.)
Flammpunkt
230 °F · >230 °F
storage temp.
2 · 2-8°C
Löslichkeit
Chloroform (Slightly), DMSO (Slightly)
Aggregatzustand
Solid

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 4.5% (3 of 66) of reports.

Warning

H315 (95.5%): Causes skin irritation [Warning Skin corrosion/irritation];H317 (95.5%): May cause an allergic skin reaction [Warning Sensitization, Skin];H319 (75.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (68.2%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H400 (68.2%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (68.2%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard];H411 (27.3%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P261, P264, P264+P265, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 3 of 66 reports by companies.;There are 5 notifications provided by 63 of 66 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-

Hazard Traits - Endocrine Toxicity;Authoritative List - CECBP - Priority Chemicals;Report - if used as a fragrance or flavor ingredient

Council Directive (EEC) No 109/1989 (Repealed by Reg. EC No 1935/2004 (amended))

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationOxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: ACTIVE
Anwendungen · 1 Eintrag

VerwendenBisphenol F Diglycidyl Ether is an novalac glycidyl ether (NOGE). Bisphenol F Diglycidyl Ether is found in resin used as coatings for food cans. Bisphenol F Diglycidyl Ether is a toxic conatminant wit h strict limitations on the amount allowed in food products.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

1-Chlor-2,3-epoxypropan4,4'-Methylendiphenol

Anbieter49 Anbieter

上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
浙江珲达生物科技有限公司0571-89903022 18679456698 · [email protected]
Aladdin Scientific[email protected]
梯希爱(上海)化工贸易有限公司021-61109150 · [email protected]
常州科化生物科技有限公司0519-68985668 13685222090 · [email protected]
上海稳同科技有限公司02151600108 13062666369 · [email protected]

Zugehörige Reaktionen

1
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 972028
HRID 972028als Eduktuspto-grants-1979_07

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Auf dieser SeiteGrundinformationenNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
91511
DTXSID
DTXSID4044872
ChEMBL
CHEMBL3182674
ChEBI
CHEBI:142451
UNII
V3625OQU1K
EC Number
218-257-4、254-641-8
Nikkaji
J298.690F
Farbe
White to Off-White
BRN
5349017 · 5349017
Major Application
cleaning productscosmeticsfood and beveragespersonal care
InChI
InChI=1S/C19H20O4/c1-5-16(20-10-18-12-22-18)6-2-14(1)9-15-3-7-17(8-4-15)21-11-19-13-23-19/h1-8,18-19H,9-13H2
InChIKey
XUCHXOAWJMEFLF-UHFFFAOYSA-N
SMILES
C(C1=CC=C(OCC2CO2)C=C1)C1=CC=C(OCC2CO2)C=C1
EPA chemische Informationen
2 · Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis- (2095-03-6)

Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Reactive GroupEthers;Epoxides
Reactivity ProfileMETHYLENE BIS(PHENYLENEOXYMETHYLENE)BISOXIRANE is incompatible with strong oxidizers.
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories · 2 Einträge

Skin Irrit. 2 (95.5%);Skin Sens. 1 (95.5%);Eye Irrit. 2 (75.8%);STOT SE 3 (68.2%);Aquatic Acute 1 (68.2%);Aquatic Chronic 1 (68.2%);Aquatic Chronic 2 (27.3%)

Skin Irrit. 2 (100%);Skin Sens. 1 (100%);Eye Irrit. 2 (100%);Aquatic Chronic 2 (100%)

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.;SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.;INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.;INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill ResponseSTORAGE PRECAUTIONS: You should store this material in a refrigerator. (NTP, 1992)
Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Regulatorische Informationen

Regulatory Information · 5 Einträge

Chemical: Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-

Hazard Traits - Endocrine Toxicity;Authoritative List - CECBP - Priority Chemicals;Report - if used as a fragrance or flavor ingredient

Council Directive (EEC) No 109/1989 (Repealed by Reg. EC No 1935/2004 (amended))

Oxirane, 2,2'-[methylenebis(4,1-phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Oxirane, 2,2'-[methylenebis(phenyleneoxymethylene)]bis-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Sicherheitsdaten

wgk
3
ridadr
UN 3082 9/PG 3
risk_code
36/38-43-50/53-36/37/38
hazard_code
Xi,N
safety_code
37/39-61-60-36/37-26
Speicherklasse
11 - Combustible Solids
Hazard Classifications
Aquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Skin Irrit. 2Skin Sens. 1STOT SE 3
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