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2,2'-Dimethyl-4,4'-methylenbis-(cyclohexylamin)

Bis(4-amino-3-methylcyclohexyl)methane

HCID 91555
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Grundinformationen

CAS
6864-37-5
Standard-SMILES
CC1CC(CC2CCC(N)C(C)C2)CCC1N
InChIKey
IGSBHTZEJMPDSZ-UHFFFAOYSA-N
Summenformel
C15H30N2
Durchschnittliche Molmasse
238,41 g/mol
Monoisotopische Masse
238,24089897

Überblick

amine curing agent for epoxy resin

Namen und Bezeichner

Bevorzugter Name
Bis(4-amino-3-methylcyclohexyl)methane
IUPAC
4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine
Lokaler Name
2,2'-Dimethyl-4,4'-methylenbis-(cyclohexylamin)
Englischer Name
4,4'-Methylenebis(2-methylcyclohexylamine)
Summenformel
C15H30N2
Molmasse
238.41

Namen und Synonyme

6864-37-5Bis(4-amino-3-methylcyclohexyl)methane4,4'-Methylenebis(2-methylcyclohexylamine)3,3'-Dimethyl-4,4'-diaminodicyclohexylmethaneCyclohexanamine, 4,4'-methylenebis[2-methyl-DTXSID60296702,2'-Dimethyl-4,4'-methylenebis(cyclohexylamine)3K4H01E55XCyclohexanamine, 4,4'-methylenebis(2-methyl-DTXCID209670RefChem:120131Cyclohexanamine, 4,4'-methylene-bis(2-methyl-)
Weitere Namen anzeigen
DMDCMACM4,4'-methylenebis(2-methylcyclohexan-1-amine)3,3’-Dimethyl-4,4’-diaminodicyclohexylmethaneDMDC/MACMMACM 、DMDCDimethyldicycan
229-962-14,4'-methylenebis(2-methylcyclohexanamine)Dimethyldicyane4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine4,4''-Methylenebis[2-methylcyclohexanamine]MFCD00075535EINECS 229-962-1UNII-3K4H01E55X

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,8
Polarare Oberfläche (TPSA)
52 Ų
H-Brücken-Donoren
2
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
2
Schwere Atome
17
Formalladung
0
Komplexität
217

Experimentelle und physikochemische Eigenschaften

LogP2.5
DensityRelative density (water = 1): 0.95
SolubilitySolubility in water, g/100ml at 20 °C: 0.4
Endocrine DisruptorsPotential endocrine disrupting compound
Boiling Point342 °C
Melting Point-7 °C
Vapor PressureVapor pressure, Pa at 20 °C: 0.08
Food Contact Substances · 2 Einträge

FCS -> FDA Cumulative Estimated Daily Intake (CEDI)

FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2 Einträge

Liquid

COLOURLESS-TO-YELLOW LIQUID.

Physikochemische Eigenschaften

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P330, P361+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Cyclohexanamine, 4,4'-methylenebis[2-methyl-

Cyclohexanamine, 4,4'-methylenebis[2-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexanamine, 4,4'-methylenebis[2-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: 2,2'-dimethyl-4,4'-methylenebis(cyclohexylamine) (EC: 229-962-1)

4,4'-Methylenebis(2-methylcyclohexylamine): Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Cyclohexanamine, 4,4'-methylenebis[2-methyl-
Fire HazardsCombustible.
EC ClassificationSymbol: T, C, N; R: 22-23/24-35-51/53; S: (1/2)-26-36/37/39-45-61
Chemical DangersThe substance is a weak base. Decomposes on burning. This produces nitrogen oxides.

Chemie und Industrie

Verwendung und Herstellung

U.S. Production2023: 1,000,000 - <2,500,000 lb
Consumer UsesCatalyst
Industry UsesIntermediate
General Manufacturing Information · 2 Einträge

Not Known or Reasonably Ascertainable

Cyclohexanamine, 4,4'-methylenebis[2-methyl-: ACTIVE

Anwendungen

Verwenden4,4'-Methylenebis(2-methylcyclohexylamine) can be used as epoxy curing agents.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

4,4'-Methylenbis(2-methyl)-benzolamin

Anbieter100 Anbieter

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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湖北万得化工有限公司15377098680 15377098680 · [email protected]
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Datenbank-Bezeichner

CAS
6864-37-5
PubChem CID
91555
DTXSID
DTXSID6029670
ChEMBL
CHEMBL3189048
UNII
3K4H01E55X
EC Number
229-962-1
Nikkaji
J39.615J
Schmelzpunkt
-7 °C · -7°C
Siedepunkt
93 · 93-100 °C(lit.)
Dichte
0.94 g/mL · 0.94 g/mL at 25 °C(lit.)
Dampfdruck
0.08 Pa · 0.08Pa at 20℃
Brechungsindex
20 · n20/D 1.499(lit.)
Flammpunkt
230 °F · >230 °F
storage temp.
Keep in dark place,Inert atmosphere,Room temperature
Löslichkeit
3.6 g/l · 3.6g/l
Aggregatzustand
clear liquid
pka
11.03 · 11.03±0.70(Predicted)
Farbe
Colorless to Light yellow to Light orange
PH
11 · 11 (3.6g/l, H2O, 20℃)
Explosionsgrenze
0.5 · 0.5-2.8%(V)
Wasserlöslichkeit
2.01 g/L · 2.01g/L at 20℃
InChI
1S/C15H30N2/c1-10-7-12(3-5-14(10)16)9-13-4-6-15(17)11(2)8-13/h10-15H,3-9,16-17H2,1-2H3
InChIKey
IGSBHTZEJMPDSZ-UHFFFAOYSA-N
SMILES
CC1CC(CCC1N)CC2CCC(N)C(C)C2
LogP
2.3 at · 2.3 at 23℃
CAS Datenbank
6864 · 6864-37-5(CAS DataBase Reference)
EPA chemische Informationen
4 · Cyclohexanamine, 4,4'-methylenebis[2-methyl- (6864-37-5)
Packaging and LabellingDo not transport with food and feedstuffs.
Hazard Classes and Categories · 5 Einträge

Acute Tox. 4 (100%)

Skin corrosion - category 1A

Acute toxicity (Oral) - Category 4

Hazardous to the aquatic environment (Acute) - Category 2

Acute Tox. 3 *

Sicherheit und Schutzausrüstung

Fire FightingUse water spray, powder, alcohol-resistant foam, carbon dioxide.
First Aid Measures · 4 Einträge

Fresh air, rest. Refer for medical attention. Half-upright position. Artificial respiration may be needed.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

Safe StorageSeparated from food and feedstuffs.
Spillage DisposalConsult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible.
Eye PreventionWear face shield or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskA harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20 °C; on spraying or dispersing, however, much faster.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionAVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Ingestion PreventionDo not eat, drink, or smoke during work. Wash hands before eating.
Inhalation PreventionUse ventilation, local exhaust or breathing protection.
Effects of Long Term Exposure · 1 Eintrag

The substance may have effects on the skin. This may result in chronic disease (scleroderma). The substance may have effects on the blood, cardiovascular system, kidneys and liver. This may result in anaemia, cardiac disorders, kidney impairment and liver impairment.

Toxikologische Informationen

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.
Signs and Symptoms · 4 Einträge

Burning sensation. Cough. Sore throat. Laboured breathing. Shortness of breath. Symptoms may be delayed.

Serious skin burns. Pain. Redness.

Pain. Redness. Severe deep burns.

Abdominal pain. Burning sensation. Shock or collapse.

ICSC Environmental DataThe substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 2927 6.1/PG 2
hs_code
29213000
risk_code
22-23/24-35-51/53
Toxizität
LC50 ihl-rat: 420 mg/m3/4H NTIS** OTS0539620-1
hazard_code
T,C,N
safety_code
26-36/37/39-45-61
hazard_class
8
packing_group
II
Speicherklasse
6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 3 DermalAcute Tox. 4 OralAquatic Chronic 2Skin Corr. 1A
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