(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
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Grundinformationen
- CAS
38465-86-0- Standard-SMILES
C1=CCC/C=C\CC1.CP(c1ccccc1)c1ccccc1.CP(c1ccccc1)c1ccccc1.F[P-](F)(F)(F)(F)F.[Ir]- Summenformel
- C34H38F6IrP3
- Durchschnittliche Molmasse
- 845,79 g/mol
Namen und Bezeichner
- Bevorzugter Name
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Englischer Name
- (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
- Summenformel
- C34H38F6IrP3
- Molmasse
- 845.79
Namen und Synonyme
methyl(diphenyl)phosphane(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i)1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
Datenbank-Bezeichner
- CAS
38465-86-0- PubChem CID
- 92132755
- EC Number
- 623-615-1
Eigenschaften
Physikochemische Eigenschaften
- Schmelzpunkt
- 224 °C · 224 °C (dec.) (lit.)
- storage temp.
- 2 · under inert gas (nitrogen or Argon) at 2-8°C
- Löslichkeit
- 2 Cl2; · sol CH2Cl2; insol diethyl ether and hexanes.
- Aggregatzustand
- Crystalline Powder
- Farbe
- Red
- Wasserlöslichkeit
- Soluble in acetone. Insoluble in water.
- InChI
- 1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
- InChIKey
- LXKHQEQLBSJJCO-JXNOXZOESA-N
- SMILES
- [Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
Sicherheitsdaten
- wgk
- 3
- hs_code
- 28439000
- risk_code
- 20/21/22-36/37/38
- hazard_code
- Xn
- safety_code
- 26-36
- Speicherklasse
- 11 - Combustible Solids
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Irrit. 2Skin Irrit. 2STOT SE 3
Chemie und Industrie
Anwendungen
Verwenden(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.
Verwenden(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate is used as a reagent for isomerization of allylic alcohols and ethers; hydrogenation catalyst.
Darstellung
synthetischePreparative Methods of (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate: to a suspension of [Ir(μ-Cl)(1,5-cod)]2 (0.2 g) in 10 mL of ethanol is added methyldiphenylphosphine (0.2 g) in ethanol. The mixture is stirred for ca. 10 min until the original suspension has dissolved. To this is added excess NH4PF6 in ethanol. After cooling to 0 °C the precipitate is filtered, washed with ethanol and then ether to give the title reagent (0.36 g) as red prisms[1].
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