Tetrahydrofurfuryl acrylate
Tetrahydrofuran acrylate · sr285 · Oxolan-2-ylmethyl prop-2-enoate · (tetrahydrofuran-2-yl)Methyl acrylate · viscoat150 · sartomer302 · sartomer285 · kayaradtc101
Identifikatoren & physikalische Daten
| CAS No. | 2399-48-6 |
|---|---|
| Summenformel | C8H12O3 |
| Durchschnittliche Molmasse | 156,18 g/mol |
| Monoisotopische Masse | 156,07864424 g/mol |
| SMILES | C=CC(=O)OCC1CCCO1 |
| InChIKey | YNXCGLKMOXLBOD-UHFFFAOYSA-N |
| PubChem CID | 94232 |
| ChEMBL | CHEMBL3187472 |
| EC No. | 219-268-7 |
| DTXSID | DTXSID8044884 |
Chemische & physikalische Eigenschaften
| XLogP | 1,1 |
|---|---|
| Polarare Oberfläche (TPSA) | 35,5 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 3 |
| Frei drehbare Bindungen | 4 |
| Schwere Atome | 11 |
| Formalladung | 0 |
| Komplexität | 153 |
| Siedepunkt | 188.6 °F87 °C/9 mmHg (lit.) |
| Physical Description | LiquidOther SolidClear liquid with a musty odor. |
| Dichte | 1.064 g/mL at 25 °C (lit.) |
| Dampfdruck | 1.19hPa at 25℃ |
| Brechungsindex | n20/D 1.46(lit.) |
| Flammpunkt | >230 °F |
| Lagerbedingungen | Sealed in dry,Room Temperature |
| Löslichkeit | Soluble in water79.1g/L at 20.9℃ |
| Aggregatzustand | clear liquid |
| Farbe | Colorless to Almost colorless |
| BRN | 113115 |
| Kosmetik-Inhaltsstoffe Funktionen | VISCOSITY CONTROLLING |
| InChI | 1S/C8H12O3/c1-2-8(9)11-6-7-4-3-5-10-7/h2,7H,1,3-6H2 |
| InChIKey | YNXCGLKMOXLBOD-UHFFFAOYSA-N |
| SMILES | C=CC(=O)OCC1CCCO1 |
| LogP (Verteilungskoeffizient) | 0.81 at 21.7℃ |
| CAS Datenbank | 2399-48-6(CAS DataBase Reference) |
| EPA chemische Informationen | Tetrahydrofurfuryl acrylate (2399-48-6) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 3.7% (16 of 434) of reports.DangerH302 (47.9%): Harmful if swallowed [Warning Acute toxicity, oral]P203, P260, P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P318, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 434 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: 2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, (tetrahydro-2-furanyl)methyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 01-07-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/201492-Propenoic acid, (tetrahydro-2-furanyl)methyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Weitere Sicherheitsinformationen | Evaluation - Tetrahydrofurfuryl acrylate and tetrahydrofurfuryl methacrylate |
| Hazard Classes and Categories | Acute Tox. 4 (47.9%)Acute toxicity (Oral) - Category 4 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | 3334 |
| Zollcode | 29321900 |
| RTECS-Nr. | UD3670893 |
| R-Sätze (R) | 36/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26 |
| Gefahrenklasse | 9Aquatic Chronic 3Eye Irrit. 2Skin Irrit. 2 |
| Lagerklasse | 10 - Combustible liquids |
Anwendungen & Verwendung
Verwenden
Tetrahydrofurfuryl acrylate may be used as an acrylic matrix for silver nanoparticles/polymer nanocomposites . It can form copolymers with butadiene. Prior to transfer printing, cellulosic and proteinic fibers are grafted with THFA.
Verwenden
Tetrahydrofurfuryl acrylate (THFA) can be used to prepare bio-based photopolymers. A series of thermostable shape memory photopolymers were synthesised from a mixture of two bio-based monomers, THFA and tridecyl methacrylate, with the addition of a small amount of 1,3-benzodithiol. Ethyl phenylphosphonate (2,4,6 trimethylbenzoyl) was used as a photoinitiator. The biorenewable carbon content of these photopolymers ranged from (63.7-74.9) %. The increase in THFA content in the photocured resins increased the light curing rate, increased the stiffness, and improved the mechanical and thermal properties of the obtained polymers. The developed bio-based photopolymers could replace petroleum-derived thermostable shape memory polymer analogues in a wide range of applications[1].