Bis(trichlormethyl)carbonat

Triphosgene

HCID 94429CAS 32315-10-9

Grundinformationen

Standard-SMILES
O=C(OC(Cl)(Cl)Cl)OC(Cl)(Cl)Cl
InChIKey
UCPYLLCMEDAXFR-UHFFFAOYSA-N
Summenformel
C3Cl6O3
Durchschnittliche Molmasse
296,7 g/mol
Monoisotopische Masse
293,79785994

Namen und Bezeichner

Bevorzugter Name
Triphosgene
IUPAC
bis(trichloromethyl) carbonate
Lokaler Name
Bis(trichlormethyl)carbonat
Englischer Name
Triphosgene
Summenformel
C3Cl6O3
Molmasse
296.73

Namen und Synonyme

Triphosgene32315-10-9Bis(trichloromethyl) carbonateMethanol, trichloro-, carbonate (2:1)2C0677Q3B2DTXSID00865631RefChem:120279DTXCID40814022250-986-3bis(trichloromethyl)carbonateditrichloromethyl carbonateC3Cl6O3
Weitere Namen anzeigen
TriphosgTriphosgene, BTCBIS(TRICHLOROMETHYL) CARBONATE FOR SYNTHTriphosgene, 98% [Bis-(trichloromethyl)-carbonat]triphosqeneTriphosgene98+%Triphosgene,99%
Triphosgene (Technical grade)MFCD00062848bis-(trichloromethyl)carbonatetriphosgentri phosgenetri-PhosgeneUNII-2C0677Q3B2EINECS 250-986-3

Datenbank-Bezeichner

CAS
32315-10-9
PubChem CID
94429
DTXSID
DTXSID00865631
UNII
2C0677Q3B2
EC Number
250-986-3
Nikkaji
J24.122I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
4,4
Polarare Oberfläche (TPSA)
35,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
2
Schwere Atome
12

Experimentelle und physikochemische Eigenschaften

SpringerMaterials PropertiesCrystal structure

Physikochemische Eigenschaften

Schmelzpunkt
79 · 79-83 °C (lit.)
Siedepunkt
203 · 203-206 °C (lit.)
Dichte
1.78 · 1.78
Dampfdruck
16 hPa · 16 hPa (90 °C)
Flammpunkt
203 · 203-206°C
storage temp.
2 · 2-8°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H314 (93.3%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P271, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 60 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Status: Active Update: 21-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/34621

Bis(trichloromethyl) carbonate: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesSkin Corr. 1B (93.3%)

Sicherheitsdaten

F
10-19-21
wgk
2
tsca
TSCA listed
ridadr
UN 2928 6.1/PG 2
hs_code
29209010
risk_code
26-34-29-36/37/38-20/21/22-23/24/25

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationMethanol, 1,1,1-trichloro-, 1,1'-carbonate: ACTIVE
Anwendungen · 2 Einträge

BeschreibungTriphosgene is also known as solid phosgene. Its chemical name is bis (Trichloromethyl) carbonate, and its English name is bisgriehloromethyl) carbonate or triphosgene, abbreviated as BTC. Triphosgene is a white crystal, similar to the smell of phosgene. It is mainly used to synthesize chloroformate, isocyanate, polycarbonate and acyl chloride. It is widely used as an intermediate in plastics, medicine, herbicides and pesticides.

VerwendenTriphosgene is used as a carbonylating agent for aza-peptide synthesis. It reacts with several alfa-amino acids to give the corresponding N-carboxyanhydrides. It is involved in the preparation of the esterification coupling reagent, di-2-thienyl carbonate from 2(5H)-thiophenone. Further, it is used as a reagent in organic synthesis and converts an amino group into isocyanate. In addition to this, it is employed in the preparation of 2-chloronicotinaldehydes through cyclization of the corresponding enamides. It is considered as a useful substitute for phosgene.

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