4-Fluortoluol

770.4；775；775；787

777.7；756

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H302 (20.9%): Harmful if swallowed [Warning Acute toxicity, oral]；H312 (20.9%): Harmful in contact with skin [Warning Acute toxicity, dermal]；H315 (77.5%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (77.5%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H332 (40.6%): Harmful if inhaled [Warning Acute toxicity, inhalation]；H335 (58.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 187 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Chemical: Benzene, 1-fluoro-4-methyl-

4-Fluorotoluene: Does not have an individual approval but may be used under an appropriate group standard

Get medical aid.；INHALATION: Move to fresh air. Remove contaminated clothing. Keep warm and quiet. If breathing has stopped give artificial respiration.；EYES AND SKIN: Wash with plenty of water.；INGESTION: Give one or two glasses of water or milk. Induce vomiting. Give cathartics. (USCG, 1999)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:；ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.；LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2024)

Excerpt from ERG Guide 130 [Flammable Liquids (Water-Immiscible / Noxious)]:；IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.；LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).；FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Chemical: Benzene, 1-fluoro-4-methyl-

4-Fluorotoluene: Does not have an individual approval but may be used under an appropriate group standard