HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Dimethylether-Bortrifluorid
C2H6BF3O · BORON TRIFLUORIDE-METHYL · borontrifluoridecompoundwith · (Dimethyl ether)trifluoroboron · BORON TRIFLUORIDE METHYL ETHER · BORON TRIFLUORIDE-DIMETHYL ETHER · BORON TRIFLUORIDE METHYL ETHERATE · dimethyl ether--boron trifluoride
Identifikatoren & physikalische Daten
| CAS No. | 353-42-4 |
|---|---|
| Summenformel | C2H6BF3O |
| Durchschnittliche Molmasse | 113,88 g/mol |
| Monoisotopische Masse | 114,0463795 g/mol |
| SMILES | COC.FB(F)F |
| InChIKey | KTPWETRNSUKEME-UHFFFAOYSA-N |
| PubChem CID | 9621 |
| DTXSID | DTXSID60893071 |
| Lokaler Name | Dimethylether-Bortrifluorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 9,2 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 4 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 7 |
| Formalladung | 0 |
| Komplexität | 10,8 |
| Schmelzpunkt | −15 °C (lit.) |
| Siedepunkt | 126-127 °C (lit.) |
| Dichte | 1.239 g/mL at 25 °C (lit.) |
| Dampfdruck | 2.99hPa at 20℃ |
| Brechungsindex | n 20/D 1.308 (lit.) |
| Flammpunkt | 62 °C - closed cup |
| Lagerbedingungen | water-free area |
| Aggregatzustand | liquid |
| Farbe | Clear brownish |
| Wichte | 1.225 |
| Explosionsgrenze | 21.6% |
| Löslichkeit | reacts |
| BRN | 3613739 |
| InChI | 1S/C2H6BF3O/c1-7(2)3(4,5)6/h1-2H3 |
| InChIKey | FOWZWMGLMYVYDH-UHFFFAOYSA-N |
| SMILES | C[O+](C)[B-](F)(F)F |
| EPA chemische Informationen | Boron trifluoride compound with methyl ether (1:1) (353-42-4) |
Sicherheit & Vorschriften
| F | 10 |
|---|---|
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2965 |
| Zollcode | 29319090 |
| RTECS-Nr. | ED8400000 |
| R-Sätze (R) | 14/15-34-48/23-20/22 |
| Gefahrensymbole | F,C,T |
| Sicherheitshinweise (S) | 16-26-28-36/37/39-45-8-43-28A-23 |
| Gefahrenklasse | 4.3Acute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1Skin Corr. 1ASTOT RE 2 InhalationSTOT SE 3Water-react 1 |
| Verpackungsgruppe | I |
| Lagerklasse | 4.3 - Hazardous materials which set free flammable gases upon contact with water |
| Gefahrstoffdaten | 353-42-4(Hazardous Substances Data) |
| Selbstentzündungstemperatur | 455 °F |
Anwendungen & Verwendung
Verwenden
Reactant or reagent involved in:Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchangeSynthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactionsSynthesis of peloruside via lactonization and relay ring-closing metathesis cyclizationFRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactionsSingle molecuel imaging of fluorophore-tagged palldium(II) complexesβ-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers