Fluoracetylchlorid

Fluoroacetyl chloride

HCID 9663CAS 359-06-8

Grundinformationen

Standard-SMILES
O=C(Cl)CF
InChIKey
ZBHDTYQJAQDBIH-UHFFFAOYSA-N
Summenformel
C2H2ClFO
Durchschnittliche Molmasse
96,49 g/mol
Monoisotopische Masse
95,97782058

Überblick

Fluoroacetyl chloride is a liquid. (EPA, 1998)

Namen und Bezeichner

Bevorzugter Name
Fluoroacetyl chloride
IUPAC
2-fluoroacetyl chloride
Lokaler Name
Fluoracetylchlorid
Englischer Name
Fluoroacetyl chloride
Summenformel
C2H2ClFO
Molmasse
96.49

Namen und Synonyme

FLUOROACETYL CHLORIDE2-fluoroacetyl chlorideAcetyl chloride, fluoro-HSDB 6327UNII-0CQX1ANG4H0CQX1ANG4HChlorid kyseliny fluoroctoveChlorid kyseliny fluoroctove [Czech]EINECS 206-623-6Acetyl chloride, 2-fluoro-TL 670BRN 1739051
Weitere Namen anzeigen
tl670tl670[qr]fluoro-acetylchloridacetylchloride,fluoro-fluoroacetylchloride101fluoroacetylchloride[qr]Acetyl chloride,2-fluoro2-fluoroethanoyl chloride
DTXSID40598854-02-00-00454 (Beilstein Handbook Reference)FLUOROACETYL CHLORIDE [HSDB]Acetyl chloride, fluoroRefChem:140914DTXCID4039104206-623-6359-06-8

Datenbank-Bezeichner

CAS
359-06-8
PubChem CID
9663
DTXSID
DTXSID4059885
UNII
0CQX1ANG4H
EC Number
206-623-6
Nikkaji
J55.073F

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,1
Polarare Oberfläche (TPSA)
17,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
1
Schwere Atome
5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesToxic Gases & Vapors -> Acid Halides
SpringerMaterials PropertiesBoiling point
Boiling Point73 °C @760 [mm Hg]
Vapor Pressure80 [mm Hg] @25 °C
Physical Description · 2 Einträge

Fluoroacetyl chloride is a liquid. (EPA, 1998)

Liquid; [CAMEO] Clear liquid; [MSDSonline]

Physikochemische Eigenschaften

Siedepunkt
71 °C · 71°C
Dichte
1.38 · 1.38
EPA chemische Informationen
Fluoroacetyl chloride (359-06-8)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Acetyl chloride, fluoro-: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison
Fire Hazards · 1 Eintrag

When heated to decomposition, it emits very toxic fumes of chlorine and fluorine-containing compounds. (Non-Specific -- Chloroacetyl Chloride and Fluoroacetic Acid) Some of these materials may ignite combustibles (i.e., wood, paper, oil, etc.) or react violently with water. (EPA, 1998)

Health HazardsHighly toxic by inhalation. (Non-Specific -- Chloroacetyl Chloride) Corrosive to skin and irritating to eyes. (EPA, 1998)
Hazards Summary · 1 Eintrag

Ingestion could result in fluoracetate poisoning; [HSDB] Reacts with water producing hydrogen chloride; Highly toxic by inhalation; Has corrosive effects to skin and irritates eyes; [CAMEO] Forms hydrogen chloride on contact with moisture; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; [MSDSonline] See Sodium fluoroacetate.

Reactive GroupHalogenated Organic Compounds

Sicherheit und Schutzausrüstung

Fire Fighting · 1 Eintrag

(Non-Specific -- Chloroacetyl Chloride and Fluoroacetic Acid) Spray cooling water on containers that are exposed to flames until well after fire is out. Move container from fire area if you can do so without risk. Do not get water in container, as material may react violently with water.

First Aid · 1 Eintrag

Warning: There is no known antidote for fluoroacetate intoxication. Symptomatic and supportive care should be provided. Highly toxic by inhalation; corrosive to the skin and irritating to the eyes. Delayed convulsant. Effects usually appear within 30 minutes of exposure but may be delayed as long as 20 hours. Caution is advised. Vital signs should be monitored closely.

Nonfire Spill Response · 1 Eintrag

(Non-Specific -- Chloroacetyl Chloride and Fluoroacetic Acid) Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Do not touch spilled material; stop leak if you can do so without risk. Use water spray to reduce vapors (may react violently with water).

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Protective Action Criteria (PAC) · 3 Einträge

0.014 [mg/m3]

0.15 [mg/m3]

0.90 [mg/m3]

Personal Protective Equipment (PPE) · 1 Eintrag

For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)

Toxikologische Informationen

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Toxicity DataLC50 (mice) = 200 mg/m3/10min

Regulatorische Informationen

CERCLA Reportable Quantities · 1 Eintrag

Releases of CERCLA hazardous substances are subject to the release reporting requirement of CERCLA section 103, codified at 40 CFR part 302, in addition to the requirements of 40 CFR part 355. Fluoroacetyl chloride is an extremely hazardous substance (EHS) subject to reporting requirements when stored in amounts in excess of its threshold planning quantity (TPQ) of 10 lbs.

Sicherheitsdaten

tsca
TSCA listed
ridadr
2922
hs_code
2913000090
risk_code
14-26-35
hazard_code
C
safety_code
3/7-9-38-45-53

Chemie und Industrie

Verwendung und Herstellung

Methods of ManufacturingSodium fluoroacetate... can be converted by standard procedures to typical carboxylic acid derivatives such as...fluoroacetyl chloride
General Manufacturing InformationAcetyl chloride, 2-fluoro-: ACTIVE

Anbieter31 Anbieter

杭州品高化工有限公司0571-87658025 · [email protected]
Nanjing Kaitian Chemical Co., LTD+86-13337816511 +86-13337835376 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
南京凯天化工有限公司+86 (25) 5860-8846 · [email protected]
Syntechem Co.,Ltd[email protected]

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