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Silberchlorat

Silver chlorate

HCID 9815505
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Grundinformationen

CAS
7783-92-8
Standard-SMILES
[Ag+].[O-][Cl+2]([O-])[O-]
InChIKey
FJGQDKJJJITISX-UHFFFAOYSA-N
Summenformel
AgClO3
Durchschnittliche Molmasse
191,32 g/mol
Monoisotopische Masse
189,85869

Überblick

Silver chlorate is a chlorate of silver. Silver is a metallic element with the chemical symbol Ag and atomic number 47. It occurs naturally in its pure, free form, as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. (L808, L809)

Namen und Bezeichner

Bevorzugter Name
Silver chlorate
IUPAC
silver chlorate
Lokaler Name
Silberchlorat
Englischer Name
SILVER CHLORATE
Summenformel
AgClO3
Molmasse
191.32

Namen und Synonyme

Silver chlorate7783-92-8silver(1+) chlorateArgentous chlorateUNII-O4T3J400JUO4T3J400JUchloric acid silver saltEINECS 232-034-9SILVER CHLORATE [MI]DTXSID50228454SILVER CHLORATE (AG(CLO3))CHLORIC ACID SILVER(1+) SALT (1:1)
Weitere Namen anzeigen
SILVER (I) CHLORATESILVER CHLORATE, 99.9+%Chloric acid silver(I) saltSilver chlorate >=99.9% trace metals basis
argentio chlorateRefChem:183028DTXCID70150945232-034-9silver;chloratesilver(1+) ion chlorateSCHEMBL514116SCHEMBL29419641

Datenbank-Bezeichner

CAS
7783-92-8
PubChem CID
9815505
DTXSID
DTXSID50228454
UNII
O4T3J400JU
EC Number
232-034-9
Nikkaji
J43.612G

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
57,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
5
Formalladung
0
Komplexität
36,5

Physikochemische Eigenschaften

Schmelzpunkt
230 °C · 230 °C(lit.)
Dichte
4.43 g/mL · 4.43 g/mL at 25 °C(lit.)
storage temp.
2 · 2-8°C
Löslichkeit
slightly soluble in ethanol
Aggregatzustand
white tetragonal crystals
Farbe
white tetragonal crystals, crystalline
Wasserlöslichkeit
100 g · g/100g solution H2O: 14.46 (25°C) [KRU93]; g/100g H2O: 10.4 (10°C), 15.3 (20°C), 26.8 (40°C) [LAN05]; slightly soluble alcohol [MER06]
Merck
13 · 13,8581
Major Application
PEM fuel cellsmaterial synthesis precursor
InChI
1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
InChIKey
SDLBJIZEEMKQKY-UHFFFAOYSA-M
SMILES
[Ag+].[O-]Cl(=O)=O

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H272 (100%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesOx. Sol. 2 (100%)

Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 Eintrag

Silver itself is not toxic to humans, but most silver salts are. In large doses, silver and compounds containing it can be absorbed into the circulatory system and become deposited in various body tissues, leading to argyria, which results in a blue-grayish pigmentation of the skin, eyes, and mucous membranes. Argyria is rare, and although, so far as known, this condition does not otherwise harm a person's health, it is disfiguring and usually permanent. Mild forms of argyria are sometimes mistaken for cyanosis. (L809)

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Silver and its compounds can be absorbed via inhalation, while silver compounds can also be absorbed orally and dermally. It distributes throughout the body in the blood, particularily to the liver. Insoluble silver salts are transformed into soluble silver sulfide albuminates, bind to amino or carboxyl groups in RNA, DNA, and proteins, or are reduced to metallic silver by ascorbic acid or catecholamines. Metallic silver is oxidized and may deposit in the tissues, causing arygria. Silver is eliminated primarily in the faeces. (L808)

Anwendungen

VerwendenSilver Chlorate is used in organic synthesis as an effective oxidizing agent for certain organic Compounds.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Disilber(1+)sulfatBariumchlorat

Anbieter8 Anbieter

济南源茂化工有限公司15665725027 18854103888 · [email protected]
斯百全化学(上海)有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]

Zugehörige Reaktionen

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Exposure RoutesOral (L808) ; inhalation (L808) ; dermal (L808)
Toxicity Summary · 1 Eintrag

Metallic silver is oxidized and may deposit in the tissues, causing arygria. The silver ion is known to inhibit glutathione peroxidase and NA+,K+-ATPase activity, disrupting selenium-catalyzed sulfhydryl oxidation-reduction reactions and intracellular ion concentrations, respectively. Silver nanoparticles are believed to disrupt the mitochondrial respiratory chain, causing oxidative stress, reduced ATP synthesis, and DNA damage. (L808, A243, A244, A245, A246)

Signs and Symptoms · 1 Eintrag

Exposure to high levels of silver for a long period of time may result in a condition called arygria, a blue-gray discoloration of the skin and other body tissues. Argyria is a permanent effect but does not appear to be harmful to health. Exposure to high levels of silver in the air has resulted in breathing problems, lung and throat irritation, and stomach pains. Skin contact with silver can cause mild allergic reactions such as rash, swelling, and inflammation in some people. (L808)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

wgk
3
ridadr
UN 1479 5.1/PG 2
risk_code
8-36/37/38
hazard_code
O,Xi
safety_code
17-26-36
hazard_class
5.1
packing_group
II
Speicherklasse
5.1B - Oxidizing hazardous materials
Hazard Classifications
Eye Irrit. 2Ox. Sol. 2Skin Irrit. 2STOT SE 3
陕西缔都医药化工有限公司029-029-029-81148696 18161915376 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]