Acryloylmorpholine

ACMO · ACRYLOYL MORPHOLINE · N-ACRYLOYLMORPHOLINE · 1-Morpholinoprop-2-en-1-one · 4-(1-oxo-2-propenyl)-Morpholine · yyyy-m-d · N-Acrylylmorpholine · 4-AcryL

https://huagongshe.com/de/chemical/98723

Identifikatoren & physikalische Daten

CAS No.	5117-12-4
Summenformel	C7H11NO2
Durchschnittliche Molmasse	141,17 g/mol
Monoisotopische Masse	141,07897859 g/mol
SMILES	C=CC(=O)N1CCOCC1
InChIKey	XLPJNCYCZORXHG-UHFFFAOYSA-N
PubChem CID	98723
ChEMBL	CHEMBL3187188
EC No.	418-140-1
DTXSID	DTXSID0044947

Chemische & physikalische Eigenschaften

XLogP	-0,1
Polarare Oberfläche (TPSA)	29,5
H-Brücken-Donoren	0
H-Brücken-Akzeptoren	2
Frei drehbare Bindungen	1
Schwere Atome	10
Formalladung	0
Komplexität	139
Schmelzpunkt	−35 °C(lit.)
Siedepunkt	158°C 50mm
Dichte	1.122 g/mL at 25 °C(lit.)
Dampfdruck	1.03-1.64Pa at 25-29.9℃
Brechungsindex	n20/D 1.512(lit.)
Flammpunkt	>230 °F
Lagerbedingungen	2-8°C
Löslichkeit	Soluble in water1000g/L at 20℃
Aggregatzustand	Liquid
pKa (Säurekonstante)	-1.08±0.20(Predicted)
Farbe	Colorless to yellow
BRN	119302
Kosmetik-Inhaltsstoffe Funktionen	PLASTICISER
InChI	1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2
InChIKey	XLPJNCYCZORXHG-UHFFFAOYSA-N
SMILES	C=CC(=O)N1CCOCC1
LogP (Verteilungskoeffizient)	-0.46 at 20.5-21℃
CAS Datenbank	5117-12-4(CAS DataBase Reference)
NIST chemische Informationen	N-acryloylmorpholine(5117-12-4)
EPA chemische Informationen	Morpholine, 4-(1-oxo-2-propenyl)- (5117-12-4)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH302: Harmful if swallowed [Warning Acute toxicity, oral]P260, P261, P264, P264+P265, P270, P272, P280, P301+P317, P302+P352, P305+P354+P338, P317, P319, P321, P330, P333+P317, P362+P364, and P501 (click each P-code to see the statement)H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]P260, P261, P264, P264+P265, P270, P271, P272, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P333+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Regulatorische Informationen	Chemical: Morpholine, 4-(1-oxo-2-propenyl)-PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.Status: No longer Valid Update: 10-11-2008 https://echa.europa.eu/registration-dossier/-/registered-dossier/9420Acryloyl morpholine: Does not have an individual approval but may be used under an appropriate group standard
Weitere Sicherheitsinformationen	Evaluation - Morpholine, 4-(1-oxo-2-propenyl)- (acryloyl morpholine)
Hazard Classes and Categories	Acute Tox. 4 (100%)Acute toxicity - category 4Acute toxicity (Oral) - Category 4Acute Tox. 4 *
Wassergefährdungsklasse (WGK)	2
TSCA-Inventar-Status	TSCA listed
Zollcode	29349990
R-Sätze (R)	22-41-43-48/22
Gefahrensymbole	Xn
Sicherheitshinweise (S)	23-26-36/37/39
Lagerklasse	10 - Combustible liquids
Gefahrenklasse	Acute Tox. 4 OralEye Dam. 1Skin Sens. 1STOT RE 2 Oral

Anwendungen & Verwendung

Beschreibung

4-Acryloylmorpholine (4-AM) is a water-soluble monomer, an acrylamide derivative containing a heterocyclic tetrahydrooxazine substituent. Homo- and copolymers of 4-АМ have several valuable properties. They are soluble both in water and in many organic solvents such as alcohols, chloroform, tetrahydrofuran, and dioxane, are non-toxic, and are used for solid-phase synthesis of peptides in chromatography, as materials for composite semipermeable membranes, in catalysis, and for biomedical purposes. Various functional groups are introduced into poly-4-AM to expand its application fields. Random copolymers of 4-АМ with carboxylic acids (acrylic, 4-pentenoic, undecenoic, 2-acrylamido-2-methyl-1-propanesulfonic), behaving as anionic polyelectrolytes, and copolymers with N-hydroxysuccinimide ester of acrylic acid, acting as polymeric carriers, have been synthesized[2-3].

Verwenden

4-Acryloylmorpholine is used in adhesives, UV curable resins, industrial coatings, UV printing ink, oil recovery polymer, medicinal and commodity chemicals.