2-Naphthalenecarboxylic acid, 1-hydroxy-, methyl ester → HCID 22126290, Verbindung

HRID 1005161

Reaktionsgleichung

Reaktionsgleichung von HRID 1005161
[OH:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[C:12]([O:14][CH3:15])=[O:13].[CH3:16][O:17][CH2:18][CH2:19]Br>>[CH3:16][O:17][CH2:18][CH2:19][O:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][C:3]=1[C:12]([O:14][CH3:15])=[O:13]

Komponenten

3

Edukt 2

HCID 703582-Naphthalenecarboxylic acid, 1-hydroxy-, methyl esterHCID 809722-Bromoethyl methyl ether

Produkt 1

HCID 22126290HCID 22126290, Verbindung

Versuchsvorschrift

By alkylating methyl 1-hydroxy-naphthalene-2-carboxylate analogously to Example 1 (g) with 2-bromoethyl methyl ether there was obtained methyl 1-(2-methoxy-ethoxy)-naphthalene-2-carboxylate, which was subsequently converted analogously to Example 5 (b)-(c) firstly into [1-(2-methoxy-ethoxy)-naphthalen-2-yl]-methanol and then into 2-chloromethyl-1-(2-methoxy-ethoxy)-naphthalene, which was finally obtained as a beige solid; MS: 250 (M)+.

Quellen und Nachweise

ORD-Eintrag
ord-ec1ba080094845c7805ff815c90d503a
Quelldatensatz
uspto-grants-2000_04
Patentnummer
US06051712

Verknüpfte Notizen

Wird geladen…