Ammonia → 2,6-Lutidine

HRID 1012370

Reaktionsgleichung

N.[BH3:2].C([N:5]([CH2:12][CH3:13])[C:6]1[CH:11]=[CH:10][CH:9]=C[CH:7]=1)C.B.[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.B.[N:28]1C(C)=CC=CC=1C>>[C:15]1([N:21]2[CH2:26][CH2:25][O:24][CH2:23][CH2:22]2)[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[N:5]1[C:6]([CH3:7])=[CH:11][CH:10]=[CH:9][C:12]=1[CH3:13].[NH3:28].[BH3:2]

Komponenten

Edukt 4

HCID 222Ammonia2×

HCID 83312Diethylaniline-borane

HCID 15265529(T-4)-Trihydro(4-phenylmorpholine-kappaN4)boron

HCID 178419164HCID 178419164, Verbindung

Produkt 3

HCID 79372,6-Lutidine

HCID 623394-Phenylmorpholine

HCID 419330Ammonia;borane

Versuchsvorschrift

For example, dimethylaniline borane can be reacted with ammonia to produce ammonia borane as shown below. (C6H5)(CH3)2N.BH3+NH3=(C6H5)(CH3)2N+NH3.BH3 In other examples, diethylaniline borane, phenylmorpholine borane or lutidine borane can be reacted with ammonia to form ditethylaniline and ammonia borane, phenylmorpholine and ammonia borane, or lutidine and ammonia borane.

Quellen und Nachweise

ORD-Eintrag: ord-889a1419970e4c178f8797f81dee20b9
Quelldatensatz: uspto-grants-2011_07
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07977508B2

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