Aluminum(III) Chloride → 4-Iodo-3-nitro-benzophenone

HRID 1017791

Reaktionsgleichung

Reaktionsgleichung von HRID 1017791
[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([OH:8])=O)=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].[Cl-].[Cl-].[Cl-].[Al+3]>C1C=CC=CC=1>[I:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([C:2]2[CH:10]=[CH:9][CH:5]=[CH:4][CH:3]=2)=[O:8])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]

Komponenten

4

Edukt 2

HCID 6451240Aluminum(III) ChlorideHCID 112085984-Iodo-3-nitrobenzoic acid

Produkt 1

HCID 111873024-Iodo-3-nitro-benzophenone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 241BenzeneLösungsmittel

Versuchsvorschrift

5.3 g (17 mmol) of 4-iodo-3-nitrobenzoic acid and 8.0 g (60 mmol) of aluminium trichloride are added successively to 70 ml of benzene while cooling with an ice bath. Then the mixture is stirred for 2 hours at ambient temperature, then poured into ice water, extracted with methylene chloride, dried with sodium sulphate and concentrated in vacuo.

Aufarbeitung

  1. temperaturewhile cooling with an ice bath
  2. extractionextracted with methylene chloride
  3. dry with materialdried with sodium sulphate
  4. concentrationconcentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-2af6b35e3597405292621887034b7779
Quelldatensatz
uspto-grants-2002_11
Patentnummer
US06479524B1

Verknüpfte Notizen

Wird geladen…