Imidazole → imidazole LiBETI
Reaktionsgleichung
[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:7]([F:27])([F:26])([F:25])[C:8]([S:11]([N-:14][S:15]([C:18]([F:24])([F:23])[C:19]([F:22])([F:21])[F:20])(=[O:17])=[O:16])(=[O:13])=[O:12])([F:10])[F:9]>>[NH:1]1[CH:5]=[CH:4][N:3]=[CH:2]1.[Li+:6].[C:19]([F:22])([F:21])([F:20])[C:18]([S:15]([N-:14][S:11]([C:8]([F:10])([F:9])[C:7]([F:25])([F:26])[F:27])(=[O:12])=[O:13])(=[O:16])=[O:17])([F:24])[F:23]Komponenten
3
Reaktionsbedingungen
- Temperatur
- 50 °C
Versuchsvorschrift
5.3 g of purified imidazole and 10 g of LiBETI were put into a round bottom flask and slowly stirred for 50 minutes under a nitrogen circumstance of 50° C., thereby obtaining 15.2 g of imidazole-LiBETI eutectic mixture.