Paraoxon → 4-Nitrophenol

HRID 1024655

Reaktionsgleichung

Reaktionsgleichung von HRID 1024655
[CH3:1][CH2:2][O:3][P:4]([O:9][C:10]1[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=1)([O:6][CH2:7][CH3:8])=[O:5]>CO>[P:4]([O:9][CH3:10])([O:6][CH2:7][CH3:8])([O:3][CH2:2][CH3:1])=[O:5].[CH:12]1[C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=[C:10]([OH:9])[CH:11]=1

Komponenten

4

Edukt 1

HCID 9395Paraoxon

Produkt 2

HCID 9804-NitrophenolHCID 120420Diethyl methyl phosphate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

Paraoxon, when placed in an appropriately buffered methanol solution containing La3+ ions held in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature to produce diethyl methyl phosphate and p-nitrophenol. A detailed reaction scheme is given in Scheme 1.

Aufarbeitung

  1. additioncontaining La3+ ions
  2. customheld in a sspH region between 7 and 11, underwent rapid methanolysis at ambient temperature

Quellen und Nachweise

ORD-Eintrag
ord-a4cdca6eb1ee449e847be9bd4a641d92
Quelldatensatz
uspto-grants-2014_05
Patentnummer
US08722956B2

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