Benzene → Benzaldehyde

HRID 1030019

Reaktionsgleichung

Reaktionsgleichung von HRID 1030019
[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:7]1[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1.[H][H].[CH:17]([OH:20])(C)C>>[CH2:17]([OH:20])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH:7](=[O:20])[C:14]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1.[C:10]1([C:9]2[CH:8]=[CH:3][CH:2]=[CH:1][CH:6]=2)[CH:11]=[CH:12][CH:13]=[CH:14][CH:7]=1

Komponenten

7

Edukt 4

HCID 241BenzeneHCID 3776IsopropanolHCID 9266CyclooctaneHCID 178418361HCID 178418361, Verbindung

Produkt 3

HCID 240BenzaldehydeHCID 244Benzyl AlcoholHCID 7095Biphenyl

Versuchsvorschrift

The experimental procedure was substantially the same as in Example 1 except that the amount of benzene as the starting hydrocarbon compound was decreased to 12 ml while 13.8 ml of isopropyl alcohol were replaced with 18 ml of cyclooctane as the hydrogen donor compound. The result of the analysis of the reaction mixture after completion of the reaction was that the molar yields of benzyl alcohol, benzaldehyde and biphenyl were 6624%, 350% and 8%, respectively, based on the molar amount of the rhodium complex used as the catalyst. Small amounts of cyclooctane carbaldehyde and cyclooctanemethanol were detected in the reaction mixture.

Aufarbeitung

  1. customThe result of the analysis of the reaction mixture after completion of the reaction

Quellen und Nachweise

ORD-Eintrag
ord-3b78011df78045d6b31e32042433843d
Quelldatensatz
uspto-grants-1992_04
Patentnummer
US05104504

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