Reaktionsgleichung
[H][H].[C:3]([O:6][CH2:7][CH3:8])(=[O:5])[CH3:4]>>[C:3]([O:6][CH:7]([CH:7]([O:6][C:3](=[O:5])[CH3:4])[CH3:8])[CH3:8])(=[O:5])[CH3:4]Komponenten
3
Versuchsvorschrift
A stream of hydrogen was used to transfer 5.3 mL (4.8 g) of ethyl acetate into the 16-lamp photoreactor. After irradiation for 20 h at 45° C., 1.8 g of the title product were obtained. The product was identified by comparison with the authentic compound made by hydrodimerizing vinyl acetate in the 4-lamp reactor at 25° C. to give 0.9 g of the product (52% yield) after the C--Hα to the --CO2 group.
Aufarbeitung
- customAfter irradiation for 20 h at 45° C.
Quellen und Nachweise
- ORD-Eintrag
- ord-04ed26ecea3345baa215a7606bbed57e
- Quelldatensatz
- uspto-grants-1992_04
- Patentnummer
- US05104503
Verknüpfte Notizen
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