Hydrogen Peroxide → 2-Neopentylanthraquinone

HRID 1030832Notizen

Reaktionsgleichung

C(C1C=CC=CC=1)C(C)(C)C.C1(=O)OC(=O)C2=CC=CC=C12.[CH2:23]([C:28]1[CH:44]=[CH:43][C:31]([C:32]([C:34]2[CH:42]=[CH:41][CH:40]=[CH:39][C:35]=2[C:36]([OH:38])=O)=[O:33])=[CH:30][CH:29]=1)[C:24]([CH3:27])([CH3:26])[CH3:25].OO>>[CH2:23]([C:28]1[CH:44]=[CH:43][C:31]2[C:32](=[O:33])[C:34]3[C:35](=[CH:39][CH:40]=[CH:41][CH:42]=3)[C:36](=[O:38])[C:30]=2[CH:29]=1)[C:24]([CH3:25])([CH3:26])[CH3:27]

Komponenten

Edukt 4

HCID 784Hydrogen Peroxide

HCID 6811Phthalic Anhydride

HCID 13877Benzene, (2,2-dimethylpropyl)-

HCID 140079172-(4-Neopentylbenzoyl)-benzoic acid

Produkt 1

HCID 144530162-Neopentylanthraquinone

Versuchsvorschrift

The novel compound 2-neopentylanthraquinone which is prepared by Friedel-Crafts acylation of neopentylbenzene with phthalic anhydride and subsequent cyclization of the resulting 2-(4-neopentylbenzoyl)-benzoic acid in the presence of a strong, anhydrous acid, is a catalyst for the preparation of hydrogen peroxide.

Quellen und Nachweise

ORD-Eintrag: ord-e81ab080b4ea487aa92c3326c0672ac3
Quelldatensatz: uspto-grants-1992_04
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05107004

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