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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1030843Erstellt: 26. Oktober 2026

Mesitylene → 2-Acetyl-6-methoxynaphthalene

https://huagongshe.com/reaction/1030843

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktMesityleneHCID 7947—
Edukt1-Bromo-2-methoxynaphthaleneHCID 72860—
Edukt1-(5-Bromo-6-methoxynaphthalen-2-yl)ethan-1-oneHCID 622178—
EduktAluminum(III) ChlorideHCID 6451240—
Produkt2-Acetyl-6-methoxynaphthaleneHCID 77506—

Reaktionsbedingungen

Temperatur0 °C

Reaktionsschritte

51 Ml of mesitylene and 8.2 g of anhydrous aluminum chloride are added to the solution of 2-acetyl-5-bromo-6-methoxynaphthalene obtained as in example 1a), while keeping the temperature at -10° C. The reaction mixture is kept for 3 hours under stirring at 0° C. and then it is worked as in example 1 obtaining 43.2 g of product with a yield equal to 88.2% calculated on the basis of the starting material 1-bromo-2-methoxynaphthalene.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05107013
Quelldatensatzuspto-grants-1992_04
ORD IDord-86812214cd644626a512c47d35e41acc
Quellennotizuspto-grants-1992_04