Carbon Disulfide → HCID 178446353, Verbindung

HRID 1032865

Reaktionsgleichung

Reaktionsgleichung von HRID 1032865
[OH-].[Na+].[CH2:3]([NH:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:4][CH2:5][CH2:6][CH3:7].[C:14](=[S:16])=[S:15].[W:17](Cl)(Cl)(Cl)(Cl)(Cl)Cl>CO>[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[CH2:9]([N:8]([CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])[C:14](=[S:15])[S-:16])[CH2:10][CH2:11][CH2:12][CH3:13].[W+6:17]

Komponenten

6

Edukt 4

HCID 6348Carbon DisulfideHCID 14798Sodium HydroxideHCID 16316DipentylamineHCID 83301Tungsten hexachloride

Produkt 1

HCID 178446353HCID 178446353, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel2×

Versuchsvorschrift

0.576 kg of granulated caustic soda is added to 8 liters of anhydrous methanol and the mixture is stirred until all solid material has dissolved. 2.26 kg of diamylamine are added to the solution and 0.88 liter of carbon disulfide is introduced over a period of 2 hours. The mixture is stirred for a further 3 hours at 25° C. and a solution of 0.952 kg of tungsten hexachloride in 2.4 liters of anhydrous methanol is then added over a period of one hour and the mixture is stirred for an additional 3 hours.

Aufarbeitung

  1. dissolutionhas dissolved
  2. additionis introduced over a period of 2 hours
  3. stirringThe mixture is stirred for a further 3 hours at 25° C.
  4. stirringthe mixture is stirred for an additional 3 hours

Quellen und Nachweise

ORD-Eintrag
ord-509824005bfb4f039a021a270549f27e
Quelldatensatz
uspto-grants-1994_05
Patentnummer
US05308519

Verknüpfte Notizen

Wird geladen…