2-Bromo-6-methoxynaphthalene → 2-Methoxy-6-(4-methoxyphenyl)naphthalene

HRID 1035600

Reaktionsgleichung

Reaktionsgleichung von HRID 1035600
Br[C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[C:7]([O:12][CH3:13])[CH:8]=2)[CH:3]=1.[CH3:14][O:15][C:16]1[CH:21]=[CH:20][C:19](OB(O)O)=[CH:18][CH:17]=1>>[CH3:13][O:12][C:7]1[CH:6]=[CH:5][C:4]2[C:9](=[CH:10][CH:11]=[C:2]([C:19]3[CH:20]=[CH:21][C:16]([O:15][CH3:14])=[CH:17][CH:18]=3)[CH:3]=2)[CH:8]=1

Komponenten

3

Edukt 2

HCID 787862-Bromo-6-methoxynaphthaleneHCID 147699944-Methoxyphenyl boric acid

Produkt 1

HCID 111497342-Methoxy-6-(4-methoxyphenyl)naphthaleneAusbeute 56 %

Versuchsvorschrift

The compound is prepared by the reaction of 2-bromo-6-methoxynaphthalene (500 mg, 2.11 mmol, 1 eq) with 4-methoxyphenylboric acid (313 mg, 2.12 mmol, 1 eq) according to method A in 5 h. The desired product was precipitated from hexane in a yield of 56% (311 mg).

Aufarbeitung

  1. customThe desired product was precipitated from hexane in a yield of 56% (311 mg)

Quellen und Nachweise

ORD-Eintrag
ord-d5b24212f965472aa7aa059a5de8cdb2
Quelldatensatz
uspto-grants-2013_10
Patentnummer
US08546392B2

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