HCID 178435547, Verbindung → HCID 178435533, Verbindung
Reaktionsgleichung
[C:1]([C@H:5]1[CH2:10][CH2:9][C@H:8]([O:11][C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][CH:16]=[C:17]([CH:22]([N+:24]([O-:26])=[O:25])[CH3:23])[CH:18]=3)[CH:13]=2)[CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2].BrC1C=C2C(=CC=1)C([C:38]([F:41])([F:40])[F:39])=C(O[C@H]1CC[C@H](C(C)(C)C)CC1)C=C2>>[C:1]([C@H:5]1[CH2:10][CH2:9][C@H:8]([O:11][C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][CH:16]=[C:17]([CH:22]([N+:24]([O-:26])=[O:25])[CH3:23])[CH:18]=3)[C:13]=2[C:38]([F:41])([F:40])[F:39])[CH2:7][CH2:6]1)([CH3:2])([CH3:3])[CH3:4]Komponenten
3
Versuchsvorschrift
2-(trans-4-tert-butylcyclohexyloxy)-6-(1-nitroethyl)-1-(trifluoromethyl)naphthalene was synthesized as per 2-(trans-4-tert-butylcyclohexyloxy)-6-(1-nitroethyl)naphthalene (Example 204) in 35% yield using 6-bromo-2-(trans-4-tert-butylcyclohexyloxy)-1-(trifluoromethyl)naphthalene as starting material.
Quellen und Nachweise
- ORD-Eintrag
- ord-123eefd58a164ad39b1a7ad16a46e9a9
- Quelldatensatz
- uspto-grants-2013_10