Benzene, 1-bromo-3-iodo- → 9-(3-Bromophenyl)phenanthrene

HRID 1045287Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1045287
[CH:1]1[C:14]2[CH:13]=[C:12](B(O)O)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Br:18][C:19]1[CH:20]=[C:21](I)[CH:22]=[CH:23][CH:24]=1>>[Br:18][C:19]1[CH:24]=[C:23]([C:12]2[C:11]3[C:6]([C:5]4[CH:4]=[CH:3][CH:2]=[CH:1][C:14]=4[CH:13]=2)=[CH:7][CH:8]=[CH:9][CH:10]=3)[CH:22]=[CH:21][CH:20]=1

Komponenten

3

Edukt 2

HCID 11561Benzene, 1-bromo-3-iodo-HCID 117757049-Phenanthracenylboronic acid

Produkt 1

HCID 221380359-(3-Bromophenyl)phenanthrene

Versuchsvorschrift

9-(3-Bromophenyl)phenanthrene was synthesized by the same method, except that in Synthetic Example 1, 9-phenanthreneboronic acid was used in place of 2-naphthaleneboronic acid and that 3-bromoiodobenzene was used in place of 4-bromoiodobenzene.

Quellen und Nachweise

ORD-Eintrag
ord-e987247cc5134291bff3841394976359
Quelldatensatz
uspto-grants-2013_10
Patentnummer
US08568902B2

Notizen zur Reaktion

Wird geladen…