Acetate → 4'-{[4-butyl-1-(3-{[tert-butyl(dimethyl)silyl]oxy}-2,3-dihydro-1H-inden-5-yl)-2-methyl-6-oxo-1,6-dihydropyrimidin-5-yl]methyl}biphenyl-2-carbonitrile

HRID 104913

Reaktionsgleichung

Reaktionsgleichung von HRID 104913
[C:28]([CH3:29])([CH3:30])([CH3:31])[Si:32]([O:33][CH:34]1[CH2:35][CH2:36][c:37]2[cH:38][cH:39][c:40]([B:43]([OH:44])[OH:45])[cH:41][c:42]21)([CH3:46])[CH3:47].[C:70]([O-:71])(=[O:72])[CH3:73].[C:75]([O-:76])(=[O:77])[CH3:78].[CH2:1]([CH2:2][CH2:3][CH3:4])[c:5]1[n:6][c:7]([CH3:27])[nH:8][c:9](=[O:26])[c:10]1[CH2:11][c:12]1[cH:13][cH:14][c:15](-[c:18]2[c:19]([C:24]#[N:25])[cH:20][cH:21][cH:22][cH:23]2)[cH:16][cH:17]1.[CH2:61]([Cl:62])[Cl:63].[CH3:48][CH2:49][N:50]([CH2:51][CH3:52])[CH2:53][CH3:54].[CH3:64][CH2:65][O:66][C:67](=[O:68])[CH3:69].[Cu+2:74].[cH:55]1[cH:56][cH:57][n:58][cH:59][cH:60]1>>[CH2:1]([CH2:2][CH2:3][CH3:4])[c:5]1[n:6][c:7]([CH3:27])[n:8](-[c:40]2[cH:39][cH:38][c:37]3[c:42]([cH:41]2)[CH:34]([O:33][Si:32]([C:28]([CH3:29])([CH3:30])[CH3:31])([CH3:46])[CH3:47])[CH2:35][CH2:36]3)[c:9](=[O:26])[c:10]1[CH2:11][c:12]1[cH:13][cH:14][c:15](-[c:18]2[c:19]([C:24]#[N:25])[cH:20][cH:21][cH:22][cH:23]2)[cH:16][cH:17]1

Komponenten

9

Edukt 8

HCID 175Acetate2×HCID 1049PyridineHCID 6344DichloromethaneHCID 8471TriethylamineHCID 8857Ethyl AcetateHCID 27099Cupric cationHCID 57460619(3-{[tert-butyl(dimethyl)silyl]oxy}-2,3-dihydro-1H-inden-5-yl)boronic acidHCID 1354012224'-[(4-Butyl-2-methyl-6-oxo-1,6-dihydropyrimidin-5-yl)methyl]biphenyl-2-carbonitrile

Produkt 1

HCID 574606214'-{[4-butyl-1-(3-{[tert-butyl(dimethyl)silyl]oxy}-2,3-dihydro-1H-inden-5-yl)-2-methyl-6-oxo-1,6-dihydropyrimidin-5-yl]methyl}biphenyl-2-carbonitrile

Quellen und Nachweise

ORD-Eintrag
ord-2b3b3664a1a24fab8b11aaff6acb0206
Quelldatensatz
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

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