HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Pyridine → 2-(2',6'-Diisopropylphenylazo)-4-methyl-6-(9-anthracenyl)phenol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Pyridine | HCID 1049 | — |
| Edukt | Sodium Hydroxide | HCID 14798 | — |
| Edukt | Diisopropylaniline | HCID 32484 | — |
| Edukt | Phenolate | HCID 119047 | — |
| Edukt | 2-(9-Anthracenyl)-4-methylphenol | HCID 21981551 | — |
| Lösungsmittel | Benzene | HCID 241 | — |
| Lösungsmittel | Water | HCID 962 | — |
| Produkt | 2-(2',6'-Diisopropylphenylazo)-4-methyl-6-(9-anthracenyl)phenol | HCID 136104165 | — |
Reaktionsschritte
This phenol was prepared, as described above, from a theoretical yield of 3.9 mmol of diazotized 2,6-diisopropylaniline and a phenolate solution comprised of 2-(9-Anthracenyl)-4-methylphenol (0.63 g), water (20 mL), NaOH (20 mmol), pyridine (2 mL), and benzene (4 mL). In this case, the product was eluted with ether:hexanes (1:10). Yield=0.30 g (29%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07094848B2 |
| Quelldatensatz | uspto-grants-2006_08 |
| ORD ID | ord-966493f923fe4472bb4fc0c0429b9e71 |
| Quellennotiz | uspto-grants-2006_08 |