3-Chloro-5-(trifluoromethyl)-2-pyridinamine → N-(3-chloro-5-trifluoromethyl-2-pyridyl)-2,4-dinitro-3-methoxy-6-trifluoromethylaniline
Reaktionsgleichung
[NH2:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([C:9]([F:12])([F:11])[F:10])=[CH:4][N:3]=1.[N+:13]([C:16]1[C:21]([O:22][CH3:23])=[C:20]([N+:24]([O-:26])=[O:25])[CH:19]=[C:18]([C:27]([F:30])([F:29])[F:28])[C:17]=1Cl)([O-:15])=[O:14]>>[Cl:8][C:7]1[C:2]([NH:1][C:17]2[C:18]([C:27]([F:30])([F:29])[F:28])=[CH:19][C:20]([N+:24]([O-:26])=[O:25])=[C:21]([O:22][CH3:23])[C:16]=2[N+:13]([O-:15])=[O:14])=[N:3][CH:4]=[C:5]([C:9]([F:12])([F:10])[F:11])[CH:6]=1Komponenten
3
Versuchsvorschrift
In accordance with the process of Preparation 8 except using 1.9 g. of 2-amino-3-chloro-5-trifluoromethylpyridine and 2.8 g. of 2,4-dinitro-3-methoxy-6-trifluoromethylchlorobenzene, the reaction was carried out for 3 hours. The reaction mixture was treated as the process of Preparation 6 to obtain 1.4 g. of the object oily compound.
Aufarbeitung
- customIn accordance with the process of Preparation 8