HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Dinitrofluorobenzene → N-[3-(perfluorooctyl)phenyl]-2,4-dinitrobenzenamine
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Dinitrofluorobenzene | HCID 6264 | — |
| Edukt | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Edukt | 3-(Heptadecafluorooctyl)aniline | HCID 4245356 | — |
| Lösungsmittel | Triethylamine | HCID 8471 | — |
| Produkt | N-[3-(perfluorooctyl)phenyl]-2,4-dinitrobenzenamine | HCID 22735001 | 83,2% |
Reaktionsbedingungen
| Temperatur | 70 °C |
|---|
Reaktionsschritte
A mixture of 3-(perfluoro-n-octyl)benzenamine (2.04 g), 2,4-dinitrofluorobenzene (0.78 g), NMP (8 mL) and triethylamine (0.85 mL) was heated to 70° C. for 16 hr. Extraction and recrystallization from hexane-ethyl acetate gave N-[3-(perfluorooctyl)phenyl]-2,4-dinitrobenzenamine (2.25 g, mp 124.5-125° C.).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06242061B1 |
| Quelldatensatz | uspto-grants-2001_06 |
| ORD ID | ord-ea58eb06fb0644d594aaa9a577067de0 |
| Quellennotiz | uspto-grants-2001_06 |